{"id":"W1987003442","doi":"10.1016/j.susc.2007.01.024","title":"Thiolated poly(ε-caprolactone) macroligand with vacant coordination sites on gold substrate: Synthesis and surface characterization","year":2007,"lang":"en","type":"article","venue":"Surface Science","topic":"Polymer Surface Interaction Studies","field":"Materials Science","cited_by":3,"is_retracted":false,"has_abstract":false,"ca_institutions":"National Research Council Canada; York University","funders":"","keywords":"X-ray photoelectron spectroscopy; Contact angle; Substrate (aquarium); Fourier transform infrared spectroscopy; Materials science; Polymer; Microstructure; Chemical engineering; Characterization (materials science); Spectroscopy; Surface modification; Caprolactone; Polymer chemistry; Nanotechnology; Composite material; Copolymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.002102813,0.0003303699,0.0003233366,0.0001630511,0.0005919428,0.0004203022,0.0003870266,0.00008909704,0.0001397385],"category_scores_gemma":[0.000233177,0.000260718,0.00002888092,0.001157819,0.0006376007,0.001387612,0.0001194219,0.0001944092,0.0001934921],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001662934,"about_ca_system_score_gemma":0.0001481223,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002278637,"about_ca_topic_score_gemma":0.0001043841,"domain_scores_codex":[0.9970123,0.00007642044,0.00040369,0.0008480575,0.0008892837,0.0007703073],"domain_scores_gemma":[0.9982699,0.0004198086,0.0003208369,0.00039084,0.000366388,0.0002322713],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002437184,0.00005588361,0.01525921,0.00001379984,0.000008857985,0.000009887214,0.000559708,0.0001194365,0.9831043,0.0001266903,0.00002271139,0.0004757468],"study_design_scores_gemma":[0.000217495,0.000121549,0.1354799,0.00006889477,0.00001732592,0.00002284494,0.0003711148,0.0005942831,0.8626912,0.00001081571,0.0001021488,0.0003024366],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9963376,0.0001843076,0.0006462476,0.0006901277,0.0004086055,0.0003142845,0.00004172252,0.0002066345,0.001170462],"genre_scores_gemma":[0.9978711,0.00003513908,0.001208885,0.0001449165,0.00002654459,0.000004477022,0.000004264562,0.00002642128,0.0006782422],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1204131,"threshold_uncertainty_score":0.9999845,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01529101550909895,"score_gpt":0.258598037160221,"score_spread":0.2433070216511221,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}