{"id":"W1987044533","doi":"10.1021/jp901183k","title":"Theoretical Study on Reactions of HO<sub>2</sub> Radical with Photodissociation Products of Cl<sub>2</sub>SO (ClSO and SO)","year":2009,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Radical; Photodissociation; Reaction mechanism; Photochemistry; Decomposition; Intersystem crossing; Standard enthalpy of formation; Reaction intermediate; Dissociation (chemistry); Adduct; Medicinal chemistry; Physical chemistry; Organic chemistry; Excited state; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004141519,0.001231028,0.001482189,0.001059036,0.00152355,0.0007347805,0.002052718,0.001742218,0.008453785],"category_scores_gemma":[0.0005889073,0.0004410904,0.001666674,0.0009132922,0.0008053554,0.001024351,0.0009035187,0.001006768,0.0006793626],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008212106,"about_ca_system_score_gemma":0.000880472,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003888804,"about_ca_topic_score_gemma":0.003545039,"domain_scores_codex":[0.9997166,0.00007079336,0.000006164865,0.00002532287,0.00006855765,0.0001125667],"domain_scores_gemma":[0.9996588,0.0001725698,0.00003640397,0.00004112497,0.00005619118,0.00003485442],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.00027109,0.000247197,0.002719665,0.001636323,0.0001527291,0.001673546,0.0004209255,0.7416851,0.01231665,0.218226,0.003470785,0.01718004],"study_design_scores_gemma":[0.00006252137,0.0001022948,0.001265354,0.00004949448,0.000041782,0.0001606629,0.0001647025,0.9686429,0.001940883,0.02563922,0.001901195,0.00002902884],"study_design_candidate":"simulation_or_modeling","study_design_consensus":"simulation_or_modeling","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7131403,0.008052392,0.1461881,0.002047156,0.0004563949,0.0003260925,0.001550925,0.0005702948,0.1276683],"genre_scores_gemma":[0.9726634,0.00235058,0.01522232,0.0003224594,0.0001090162,0.0005085134,0.00061347,0.0001837194,0.008026538],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008453785,"threshold_uncertainty_score":0.02828074,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00637325532850534,"score_gpt":0.2088542527433626,"score_spread":0.2024809974148572,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}