{"id":"W1987175084","doi":"10.1039/b909341a","title":"Ni and Pd mediate asymmetric organoboron synthesis with ester functionality at the β-position","year":2009,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":91,"is_retracted":false,"has_abstract":true,"ca_institutions":"Mount Allison University","funders":"Ministerio de Economía y Competitividad","keywords":"Chemistry; Organoboron compounds; Catalysis; Combinatorial chemistry; Boron; Position (finance); Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001967717,0.0005507986,0.0003834155,0.00003511909,0.0004030453,0.0001488054,0.0004418546,0.0004326942,0.006989275],"category_scores_gemma":[0.0002026224,0.0004181429,0.0001168006,0.0005831125,0.0003081504,0.0001261094,0.0001837471,0.0004203632,0.0001168217],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003879096,"about_ca_system_score_gemma":0.0001592832,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000009987251,"about_ca_topic_score_gemma":0.000006770953,"domain_scores_codex":[0.9974191,0.00003270383,0.0004151376,0.0009048167,0.0006500939,0.000578122],"domain_scores_gemma":[0.9981735,0.0001235235,0.0002362334,0.001018837,0.000127972,0.000319968],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000991431,0.0001462321,0.001998233,0.0001883271,0.0001070112,0.00007589,0.00005381129,1.201884e-7,0.9944664,0.000006080286,0.0008305241,0.002028194],"study_design_scores_gemma":[0.0007652154,0.00002696473,0.002515478,0.00007357085,0.0002369506,0.0006551412,0.0001241819,0.000009904831,0.9939291,0.00004407884,0.001060305,0.0005590941],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9789667,0.001946706,0.0009961993,0.004658578,0.00007092029,0.0001380337,0.0000849217,0.0003474599,0.01279049],"genre_scores_gemma":[0.996325,0.0001652811,0.00008470915,0.0008725933,0.0002850278,0.00001922691,0.0001547007,0.00008485337,0.002008582],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01735833,"threshold_uncertainty_score":0.999827,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004283924906113485,"score_gpt":0.1932753346606968,"score_spread":0.1889914097545833,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}