{"id":"W1987547276","doi":"10.1163/15685670260188629","title":"Photocycloaddition of acetylacetonatoboron derivatives with simple olefins","year":2002,"lang":"en","type":"article","venue":"Research on Chemical Intermediates","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Difluoride; Photochemistry; Cycloaddition; Acetonitrile; Methylene; Oxalate; Singlet state; Chloride; Ether; Catalysis; Medicinal chemistry; Radical ion; Electron transfer; Ion; Organic chemistry; Excited state","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001719997,0.0002297276,0.0003233433,0.0001459375,0.00008204074,0.00003582024,0.0005033329,0.0002311638,0.01132344],"category_scores_gemma":[0.001621075,0.0001816782,0.0001158316,0.0004402557,0.001168692,0.0001352635,0.0001391294,0.00111834,0.0002087075],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002729806,"about_ca_system_score_gemma":0.00003397789,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005444355,"about_ca_topic_score_gemma":0.000006567576,"domain_scores_codex":[0.9973827,0.00004796132,0.0003641313,0.000495989,0.001058616,0.0006506055],"domain_scores_gemma":[0.9968194,0.001956527,0.0001027268,0.0005047032,0.0002551429,0.0003614662],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001810479,0.0006293334,0.0002770642,0.0001070798,0.00005449732,0.00001158443,0.0001270577,0.000002722492,0.9829397,0.0003047469,0.01328908,0.002076127],"study_design_scores_gemma":[0.0006426227,0.0001487292,0.00005883518,0.0002356486,0.000007048585,0.000007677261,0.0002352813,0.000759106,0.9883887,0.001173349,0.008151363,0.0001916106],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9484015,0.000072679,0.000008744636,0.0004647205,0.00001292704,0.0001778987,0.000113915,0.00009867395,0.05064901],"genre_scores_gemma":[0.9986711,0.000107223,0.0001569564,0.00006282297,0.00012948,0.0002508324,0.0001072515,0.00004502464,0.0004693384],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05026963,"threshold_uncertainty_score":0.9895803,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08420450757573567,"score_gpt":0.3605155424057226,"score_spread":0.2763110348299869,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}