{"id":"W1987693680","doi":"10.1002/chin.200534301","title":"2004 Bader Award Lecture Metal‐ion‐catalyzed Acyl and Phosphoryl Transfer Reactions to Alcohols: La<sup>3+</sup>‐Promoted Alcoholysis of Activated Amides, Carboxylates Esters, and Neutral Organophosphorus Esters","year":2005,"lang":"en","type":"article","venue":"ChemInform","topic":"Pesticide Exposure and Toxicity","field":"Agricultural and Biological Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Catalysis; Organic chemistry; Metal; Medicinal chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001088602,0.0009232505,0.0005262586,0.0005405915,0.000913109,0.001487614,0.0008098551,0.001683606,0.06231578],"category_scores_gemma":[0.0006570313,0.0002452245,0.0004602745,0.0003764211,0.0003030523,0.0009967235,0.0007533047,0.001231128,0.01913768],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001669298,"about_ca_system_score_gemma":0.001030997,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001049238,"about_ca_topic_score_gemma":0.002256474,"domain_scores_codex":[0.9994931,0.00004740327,0.000022191,0.00009733759,0.0001834188,0.0001565993],"domain_scores_gemma":[0.9994849,0.00004510929,0.00001756986,0.00002058721,0.0002194299,0.0002123599],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001184516,0.0004100592,0.0006480702,0.0001843163,0.00005467795,0.0004473548,0.0001135832,0.0007387513,0.05710217,0.008670752,0.7594426,0.1710031],"study_design_scores_gemma":[0.0001621262,0.0006788833,0.001516746,0.00004060559,0.00006619284,0.0003289782,0.0001649762,0.002159545,0.110147,0.002663495,0.8820224,0.00004908444],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.1047074,0.03682962,0.03305415,0.1591322,0.2311134,0.0004923566,0.002587048,0.002028546,0.4300553],"genre_scores_gemma":[0.07432265,0.006695974,0.003457685,0.002027597,0.006109294,0.00007120553,0.0009108173,0.0001312693,0.9062734],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.06231578,"threshold_uncertainty_score":0.2084671,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01091085268310886,"score_gpt":0.2128064331594028,"score_spread":0.201895580476294,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}