{"id":"W1987693874","doi":"10.1016/j.ica.2012.03.017","title":"The preparation and characterization of functionalized carboranes and Re/Tc-metallocarboranes as platforms for developing molecular imaging probes: Structural and cage isomerism studies","year":2012,"lang":"en","type":"article","venue":"Inorganica Chimica Acta","topic":"Boron Compounds in Chemistry","field":"Medicine","cited_by":21,"is_retracted":false,"has_abstract":false,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada; Government of Ontario; McMaster University","keywords":"Chemistry; Carborane; Reactivity (psychology); Steric effects; Rhenium; Ligand (biochemistry); Metal; Substituent; Stereochemistry; Crystallography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001915138,0.000170817,0.0002857157,0.00003367497,0.0001918953,0.00003852076,0.00005459175,0.00006613682,0.000003353472],"category_scores_gemma":[0.0002653848,0.0001203685,0.00002580043,0.00008306064,0.0002298531,0.0002451233,0.00008638646,0.00009525746,1.13878e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000412743,"about_ca_system_score_gemma":0.00006250873,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005221279,"about_ca_topic_score_gemma":0.000002825992,"domain_scores_codex":[0.9991203,0.00001581537,0.0003018373,0.0002163811,0.0001568558,0.0001888343],"domain_scores_gemma":[0.9992458,0.0001752983,0.000186264,0.0001782269,0.0001529297,0.00006143622],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002053468,0.000009316509,0.005282107,0.0003435787,0.0001644484,4.154294e-7,0.001388721,2.493294e-8,0.9921076,0.0002932175,0.00001556422,0.0001896183],"study_design_scores_gemma":[0.002558439,0.0001460436,0.06125654,0.0003009916,0.0004876879,0.0004339388,0.002024106,0.0005006423,0.9281321,0.001671711,0.002075245,0.0004125895],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9945462,0.00273462,0.00004158412,0.001982538,0.0001083499,0.0005041969,0.000009320486,0.00003333621,0.00003984655],"genre_scores_gemma":[0.9976737,0.000879316,0.001041452,0.000149531,0.0001164862,0.00003889209,0.00004698317,0.0000252962,0.00002836801],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06397558,"threshold_uncertainty_score":0.4908483,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0186195597067122,"score_gpt":0.3018944990332033,"score_spread":0.2832749393264911,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}