{"id":"W1987806561","doi":"10.1055/s-0034-1379537","title":"Organic Fluorine as a Hydrogen-Bond Acceptor: Recent Examples and Applications","year":2014,"lang":"en","type":"article","venue":"Synthesis","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":139,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Université Laval","keywords":"Chemistry; Hydrogen bond; Fluorine; Acceptor; Hydrogen; Hydrogen atom; Crystallography; Computational chemistry; Molecule; Organic chemistry; Group (periodic table); Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0004557366,0.0002289064,0.0002574818,0.00005137415,0.0002476211,0.00002441182,0.0003218751,0.0002694658,0.01637624],"category_scores_gemma":[0.0006357327,0.0002339272,0.00005059804,0.0002144827,0.0001932238,0.00005686365,0.0001790816,0.0003754224,0.0009899621],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007898556,"about_ca_system_score_gemma":0.00006405548,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001433486,"about_ca_topic_score_gemma":0.00001061367,"domain_scores_codex":[0.9986602,0.0001376566,0.0002813049,0.000429567,0.0001313301,0.000359943],"domain_scores_gemma":[0.9980301,0.001130156,0.0001014314,0.0004078291,0.00006050178,0.0002699332],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004487089,0.0001949997,0.002667765,0.00008062182,0.000156019,0.000003619763,0.0001215874,0.000003389194,0.783586,0.001420723,0.005454272,0.2062662],"study_design_scores_gemma":[0.0001957226,0.000014092,0.0001444561,0.000004008195,0.00009506798,0.00003425233,0.00004121699,0.00004715385,0.5268087,0.0005970245,0.4718678,0.0001505375],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9512162,0.001412729,0.000185889,0.003458063,0.0003554017,0.0005453005,0.00005152403,0.0003750559,0.04239988],"genre_scores_gemma":[0.9941928,0.0014589,0.0004954095,0.0008607579,0.0008037138,0.0002859851,0.00001546869,0.0000591901,0.001827799],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4664135,"threshold_uncertainty_score":0.9997879,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05400062717161483,"score_gpt":0.3689464005223752,"score_spread":0.3149457733507603,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}