{"id":"W1988115570","doi":"10.1021/ic000878r","title":"New Silylated Iminophosphorano(amino)phosphines Me<sub>3</sub>SiNPPh<sub>2</sub>N(R)PPh<sub>2</sub>(R = Et,<i><sup>n</sup></i>Pr,<i><sup>n</sup></i>Bu). Crystal and Molecular Structure of Trimethylsilyliminophosphorano(propylamino)diphenylphosphine Me<sub>3</sub>SiNPPh<sub>2</sub>N(<i><sup>n</sup></i>Pr)PPh<sub>2</sub>. Further Oxidative Derivatization with S, Se, and Azides, Titanium(IV) Transmetalation of the Imine, and Syntheses of Rhodium(I), Palladium(II), and Platinum(II) Complexes of These Iminophosphorano(amino)phosphines","year":2001,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Monoclinic crystal system; Crystal structure; Azide; Medicinal chemistry; Rhodium; Stereochemistry; Lone pair; Palladium; Crystallography; Trimethylsilyl; Trigonal bipyramidal molecular geometry; Amide; Molecule; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","research_integrity"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.001686928,0.005404258,0.007030762,0.0009853791,0.001408866,0.0006346656,0.002732083,0.002952338,0.000412628],"category_scores_gemma":[0.001735239,0.004936951,0.001605558,0.005224497,0.004433915,0.001971761,0.002156484,0.002739484,0.000009886416],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007211642,"about_ca_system_score_gemma":0.001796427,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006450121,"about_ca_topic_score_gemma":0.0005145959,"domain_scores_codex":[0.9799541,0.0006732561,0.006659531,0.005372892,0.004137623,0.0032026],"domain_scores_gemma":[0.9830368,0.002669118,0.005520145,0.004471095,0.002562238,0.001740675],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.003679279,0.001646328,0.008950632,0.004128406,0.00395498,0.0001428407,0.009480444,0.002056309,0.9401988,0.00009045195,0.0002703821,0.02540113],"study_design_scores_gemma":[0.008404221,0.0009603302,0.008661119,0.002481256,0.004914801,0.0008937849,0.005666769,0.004324875,0.9581027,0.0009060085,0.0001138224,0.004570314],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9735997,0.01771279,0.0008039347,0.0005724628,0.0001912068,0.003038875,0.003392894,0.0005148532,0.0001733305],"genre_scores_gemma":[0.9832049,0.01206606,0.001005632,0.0002666937,0.0004285783,0.0002133147,0.001590964,0.001162092,0.00006177291],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02083081,"threshold_uncertainty_score":0.9998912,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007479585169635725,"score_gpt":0.1972116072526348,"score_spread":0.1897320220829991,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}