{"id":"W1988115570","doi":"10.1021/ic000878r","title":"New Silylated Iminophosphorano(amino)phosphines Me<sub>3</sub>SiNPPh<sub>2</sub>N(R)PPh<sub>2</sub>(R = Et,<i><sup>n</sup></i>Pr,<i><sup>n</sup></i>Bu). Crystal and Molecular Structure of Trimethylsilyliminophosphorano(propylamino)diphenylphosphine Me<sub>3</sub>SiNPPh<sub>2</sub>N(<i><sup>n</sup></i>Pr)PPh<sub>2</sub>. Further Oxidative Derivatization with S, Se, and Azides, Titanium(IV) Transmetalation of the Imine, and Syntheses of Rhodium(I), Palladium(II), and Platinum(II) Complexes of These Iminophosphorano(amino)phosphines","year":2001,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Monoclinic crystal system; Crystal structure; Azide; Medicinal chemistry; Rhodium; Stereochemistry; Lone pair; Palladium; Crystallography; Trimethylsilyl; Trigonal bipyramidal molecular geometry; Amide; Molecule; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004975229,0.0002532143,0.00009061642,0.00008509839,0.00007071847,0.0001596397,0.0002193822,0.0001705453,0.002210333],"category_scores_gemma":[0.00009573909,0.0001329833,0.00008507543,0.00008064854,0.0001229666,0.0002659553,0.0001377641,0.0003514132,0.0005377674],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001516712,"about_ca_system_score_gemma":0.0001365533,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002064002,"about_ca_topic_score_gemma":0.0005241642,"domain_scores_codex":[0.9999664,0.000003733621,0.000002695147,0.000008625901,0.00001249208,0.000006031108],"domain_scores_gemma":[0.9999553,0.000005872754,0.00001820362,0.000004721217,0.000006944195,0.000008967245],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000447087,0.000008085995,0.00007573352,0.00006600639,0.000003794459,0.00005108041,0.00001553002,0.0001384681,0.9965796,0.0003088851,0.00008100896,0.002627204],"study_design_scores_gemma":[0.0000127522,0.0001159507,0.0008281789,0.000003902178,0.00001115527,0.0002517123,0.00001895425,0.0004526313,0.9920185,0.00008739082,0.006195542,0.000003204532],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9581851,0.003940956,0.01946141,0.0001505,0.00007681864,0.00007865595,0.0005489876,0.0004683131,0.01708915],"genre_scores_gemma":[0.9728172,0.001801071,0.01499394,0.00009031319,0.00001811598,0.00005870596,0.00065562,0.00004615263,0.009518846],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002210333,"threshold_uncertainty_score":0.007394254,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007479585169635725,"score_gpt":0.1972116072526348,"score_spread":0.1897320220829991,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}