{"id":"W1988208683","doi":"10.1021/ma0605494","title":"Unusual Rheological Behavior of Liquid Polybutadiene Rubber/Clay Nanocomposite Gels:  The Role of Polymer−Clay Interaction, Clay Exfoliation, and Clay Orientation and Disorientation","year":2006,"lang":"en","type":"article","venue":"Macromolecules","topic":"Polymer Nanocomposites and Properties","field":"Materials Science","cited_by":69,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Rheology; Exfoliation joint; Materials science; Polymer clay; Composite material; Polybutadiene; Polymer; Nanocomposite; Natural rubber; Shear (geology); Graphene; Nanotechnology; Copolymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001424719,0.0003117634,0.0002222275,0.0002657773,0.0001432969,0.0002889286,0.0001140345,0.0002499881,0.000711609],"category_scores_gemma":[0.0002417052,0.0001379729,0.0001252272,0.0001273987,0.0002356797,0.0002799941,0.0001512946,0.0004484184,0.0001337785],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001088502,"about_ca_system_score_gemma":0.00008723023,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002474147,"about_ca_topic_score_gemma":0.0004709746,"domain_scores_codex":[0.9999183,0.00000883075,0.000006108213,0.00002150068,0.00002555533,0.00001975614],"domain_scores_gemma":[0.999826,0.00004685035,0.00004475623,0.00001370715,0.0000262739,0.0000424225],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000272847,0.000005374489,0.0001566509,0.00002104601,0.000002043902,0.00003670801,0.00002125905,0.00003734216,0.9993111,0.00001182316,0.000004140606,0.0003652484],"study_design_scores_gemma":[0.000006661346,0.0001277719,0.004800217,0.000003418603,0.00001076819,0.0002391742,0.00002598115,0.001090193,0.9933868,0.00002217617,0.0002790585,0.000007845638],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9980528,0.0004217001,0.001052442,0.00002072974,0.000005943669,0.00000689151,0.00007093693,0.00003657933,0.0003319372],"genre_scores_gemma":[0.9987718,0.0001242649,0.0006597107,0.000008779141,0.000002612118,0.00000617367,0.00006124198,0.00001073913,0.0003546418],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000711609,"threshold_uncertainty_score":0.00238061,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007148708290791252,"score_gpt":0.2380384852945935,"score_spread":0.2308897770038023,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}