{"id":"W1988208683","doi":"10.1021/ma0605494","title":"Unusual Rheological Behavior of Liquid Polybutadiene Rubber/Clay Nanocomposite Gels:  The Role of Polymer−Clay Interaction, Clay Exfoliation, and Clay Orientation and Disorientation","year":2006,"lang":"en","type":"article","venue":"Macromolecules","topic":"Polymer Nanocomposites and Properties","field":"Materials Science","cited_by":69,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Rheology; Exfoliation joint; Materials science; Polymer clay; Composite material; Polybutadiene; Polymer; Nanocomposite; Natural rubber; Shear (geology); Graphene; Nanotechnology; Copolymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002445226,0.0002224292,0.0002883974,0.0001119439,0.0002471402,0.00009623537,0.0001853117,0.0001061409,0.00007082407],"category_scores_gemma":[0.00001985059,0.0001577848,0.00006619334,0.0002025237,0.000433806,0.0003137791,0.0001312277,0.00008990807,0.000005367041],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002704577,"about_ca_system_score_gemma":0.00002970904,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001650013,"about_ca_topic_score_gemma":0.00005219703,"domain_scores_codex":[0.9982575,0.0002269196,0.0005861015,0.0003731255,0.0002841341,0.0002722637],"domain_scores_gemma":[0.9990663,0.0001233753,0.0003879797,0.0002244352,0.0001331819,0.00006474004],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003052324,0.0001439807,0.01486913,0.00002454144,0.00001276474,0.000002532285,0.001044319,0.00001925422,0.9791988,0.002525182,0.0000144082,0.001839818],"study_design_scores_gemma":[0.0004033759,0.0004628988,0.01951188,0.00003859495,0.00009145845,0.00005267579,0.0003551221,0.0001258277,0.9783415,0.0003138605,0.0001204072,0.0001823613],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9940698,0.00427336,0.0003437952,0.0001666135,0.000199178,0.0003437574,0.00009011552,0.0000388439,0.0004745067],"genre_scores_gemma":[0.9991144,0.00007220664,0.000419009,0.00006366023,0.00007052624,0.00006220097,0.00006394309,0.00001935,0.0001147086],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005044565,"threshold_uncertainty_score":0.6434276,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007148708290791252,"score_gpt":0.2380384852945935,"score_spread":0.2308897770038023,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}