{"id":"W1988241433","doi":"10.1002/chin.200335219","title":"Selective Functionalization of Small Organic Molecules Using Electrophilic Nitrogen Sources","year":2003,"lang":"en","type":"article","venue":"ChemInform","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Surface modification; Electrophile; Nitrogen; Organic molecules; Small molecule; Organic chemistry; Combinatorial chemistry; Molecule; Nanotechnology; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005103874,0.0001521658,0.0001731156,0.00004739558,0.00007292066,0.00001371268,0.0001222397,0.0001565963,0.001489193],"category_scores_gemma":[0.0005442208,0.000154245,0.00009787491,0.000337462,0.00008541313,0.00008026286,0.00001954371,0.0001838029,0.00001374227],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002461329,"about_ca_system_score_gemma":0.0001719691,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001971733,"about_ca_topic_score_gemma":0.000002331763,"domain_scores_codex":[0.9990787,7.229701e-7,0.0002891243,0.0001852182,0.0002004344,0.0002457892],"domain_scores_gemma":[0.9993004,0.0000793951,0.0001640333,0.0002011126,0.0001531325,0.0001018856],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001602102,0.00005645806,0.0003853162,0.00006501414,0.00006378983,4.384098e-7,0.00007983571,0.00001380916,0.9979737,0.0005373812,0.0001632743,0.0006449498],"study_design_scores_gemma":[0.0002421528,0.00001097995,0.00001539853,0.00002235821,0.00004339339,0.00002737875,0.00008822143,0.0002272173,0.993563,0.002808046,0.002800447,0.0001514275],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7569137,0.0001649535,0.0002865186,0.00000738429,0.00002057412,0.00007491133,0.000007023187,0.00007070035,0.2424543],"genre_scores_gemma":[0.9983161,0.00001356111,0.0003718555,0.00004077048,0.00005697852,0.0000175679,0.00005126994,0.00002922279,0.001102645],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2414025,"threshold_uncertainty_score":0.9994236,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01276216501837193,"score_gpt":0.2197762288479071,"score_spread":0.2070140638295351,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}