{"id":"W1988343953","doi":"10.1021/ic990760e","title":"Bonding, Structure, and Energetics of Gaseous E<sub>8</sub><sup>2+</sup>and of Solid E<sub>8</sub>(AsF<sub>6</sub>)<sub>2</sub>(E = S, Se)","year":2000,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":77,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University; University of New Brunswick","funders":"","keywords":"Chemistry; Monoclinic crystal system; Lattice energy; Crystallography; Stoichiometry; Crystal structure; Dissociation (chemistry); Bond-dissociation energy; Solid-state; Ab initio; Standard enthalpy of formation; Exothermic reaction; Energetics; Physical chemistry; Organic chemistry; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006467165,0.0001974343,0.0001421896,0.0002419109,0.0003968059,0.0002096289,0.0003622354,0.0003063336,0.00456952],"category_scores_gemma":[0.0001426242,0.0001429226,0.000088976,0.0001984353,0.0003588829,0.0002215636,0.0002481591,0.0001638755,0.0003253201],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002478645,"about_ca_system_score_gemma":0.0001242123,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001161976,"about_ca_topic_score_gemma":0.00169608,"domain_scores_codex":[0.999953,0.000007735844,0.000001701113,0.000008745459,0.00001626409,0.00001260288],"domain_scores_gemma":[0.9999639,0.00001011818,0.000009325278,0.000003428717,0.000006591212,0.000006658828],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002448044,0.0002593778,0.05411458,0.0009679291,0.0001118088,0.00215351,0.00117834,0.05827296,0.7749735,0.05044864,0.004180337,0.05089098],"study_design_scores_gemma":[0.0003485819,0.002416974,0.1591519,0.00009456034,0.00008910272,0.002801036,0.005099074,0.2841307,0.4790395,0.03374736,0.03296101,0.0001202878],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9983259,0.00009869263,0.0002288075,0.00003065907,0.000001799085,0.000001138898,0.00005687762,0.000008162006,0.001247884],"genre_scores_gemma":[0.9985643,0.00006739163,0.0003403,0.000007985789,0.000001662604,0.000004909118,0.0001980138,0.000007453923,0.0008080775],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00456952,"threshold_uncertainty_score":0.01528662,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004334637053771807,"score_gpt":0.1924749848539057,"score_spread":0.1881403478001339,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}