{"id":"W1988430172","doi":"10.1021/ja0114106","title":"The <sup>129</sup>Xe Chemical Shift Tensor in a Silicalite Single Crystal from Hyperpolarized <sup>129</sup>Xe NMR Spectroscopy","year":2001,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Atomic and Subatomic Physics Research","field":"Physics and Astronomy","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"","keywords":"Chemistry; Nuclear magnetic resonance spectroscopy; Isotopes of xenon; Spectroscopy; Xenon; Single crystal; Nuclear magnetic resonance; Crystallography; Stereochemistry; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002959382,0.0002526488,0.0002403116,0.0005511787,0.0005214548,0.0005523407,0.0004722929,0.0005801439,0.00818743],"category_scores_gemma":[0.0009465542,0.0003041328,0.0001460278,0.0004203888,0.000551605,0.0008447712,0.000304321,0.0005244938,0.001053033],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003609697,"about_ca_system_score_gemma":0.0005518621,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001925043,"about_ca_topic_score_gemma":0.004481312,"domain_scores_codex":[0.9997492,0.00001094797,0.00001043708,0.00004428747,0.0001606002,0.00002434066],"domain_scores_gemma":[0.9994583,0.00006920997,0.00009004766,0.00005262275,0.0002521406,0.000077686],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003500278,0.00002473008,0.003599947,0.0002498405,0.00001571835,0.0005467891,0.000192834,0.0003835196,0.9774572,0.001797421,0.00402991,0.01135208],"study_design_scores_gemma":[0.00005879427,0.0001727124,0.06484871,0.0000381342,0.00005514058,0.001314165,0.0003436903,0.003876606,0.9134669,0.001112343,0.01463715,0.00007568934],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9701412,0.0005662262,0.004828905,0.001348881,0.0003036797,0.00002801752,0.001970605,0.0004422999,0.02037023],"genre_scores_gemma":[0.9728919,0.0004613239,0.005044789,0.0001857679,0.00006554937,0.0000162443,0.003173884,0.0002689932,0.01789159],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00818743,"threshold_uncertainty_score":0.02738971,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01157977947003869,"score_gpt":0.2639174922258826,"score_spread":0.2523377127558439,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}