{"id":"W1988430172","doi":"10.1021/ja0114106","title":"The <sup>129</sup>Xe Chemical Shift Tensor in a Silicalite Single Crystal from Hyperpolarized <sup>129</sup>Xe NMR Spectroscopy","year":2001,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Atomic and Subatomic Physics Research","field":"Physics and Astronomy","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"Steacie Institute for Molecular Sciences","funders":"","keywords":"Chemistry; Nuclear magnetic resonance spectroscopy; Isotopes of xenon; Spectroscopy; Xenon; Single crystal; Nuclear magnetic resonance; Crystallography; Stereochemistry; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity"],"consensus_categories":[],"category_scores_codex":[0.0006576972,0.0004949162,0.001068534,0.00003597474,0.0003338401,0.0002313894,0.00169509,0.0001468738,0.0001883837],"category_scores_gemma":[0.0001379285,0.0003123058,0.00153783,0.0008377422,0.001371216,0.0002488118,0.0005507594,0.002307721,0.00003241151],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006960168,"about_ca_system_score_gemma":0.0004745385,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006859995,"about_ca_topic_score_gemma":0.000001441977,"domain_scores_codex":[0.9959211,0.0002819521,0.00106873,0.0005251639,0.001057766,0.001145288],"domain_scores_gemma":[0.9967847,0.001101743,0.0007673298,0.0007331418,0.0001784658,0.0004346272],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008449511,0.001067683,0.06039792,0.00001006412,0.0007483157,0.00001399067,0.003110313,0.0003341822,0.9171627,0.0003134457,0.008548602,0.007447815],"study_design_scores_gemma":[0.01781515,0.0005306725,0.01179667,0.0006158651,0.0008643868,0.0001688374,0.03821377,0.3018325,0.4898389,0.08223891,0.05239191,0.003692502],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9927369,0.0001614271,0.001611143,0.004285716,0.00004027569,0.0002571148,0.00008341503,0.00002546004,0.0007984965],"genre_scores_gemma":[0.9958097,0.00006983185,0.001507826,0.0007044686,0.00165072,0.00001526981,0.00001796169,0.00007165947,0.0001525068],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4273238,"threshold_uncertainty_score":0.999994,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01157977947003869,"score_gpt":0.2639174922258826,"score_spread":0.2523377127558439,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}