{"id":"W1988574505","doi":"10.1021/om034345c","title":"β-Diketiminato Scandium Chemistry:  Synthesis, Characterization, and Thermal Behavior of Primary Amido Alkyl Derivatives","year":2004,"lang":"en","type":"article","venue":"Organometallics","topic":"Coordination Chemistry and Organometallics","field":"Chemistry","cited_by":96,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary; University of Alberta","funders":"","keywords":"Chemistry; Scandium; Metalation; Lithium amide; Ligand (biochemistry); Amide; Steric effects; Aryl; Homoleptic; Electrophile; Medicinal chemistry; Alkyl; Stereochemistry; Reagent; Isopropyl; Isostructural; Crystal structure; Crystallography; Organic chemistry; Metal","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001350146,0.0003429864,0.0004709703,0.00005951872,0.000139112,0.00006242456,0.0003403689,0.0002316075,0.004018306],"category_scores_gemma":[0.0002006516,0.0003579144,0.0001087318,0.0003824637,0.000321867,0.0002564917,0.0001787849,0.0002040801,0.00001103926],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001410435,"about_ca_system_score_gemma":0.0001659427,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006387592,"about_ca_topic_score_gemma":9.533101e-7,"domain_scores_codex":[0.9983891,0.00001293889,0.000504066,0.000459712,0.0003230616,0.0003110755],"domain_scores_gemma":[0.9987682,0.00008978699,0.0003400551,0.0004602298,0.0001685395,0.0001731704],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002396314,0.0003324081,0.003570788,0.0005057638,0.00007590457,0.000008603998,0.0002453178,0.00000417241,0.9863662,0.0001697933,0.000003048884,0.00869408],"study_design_scores_gemma":[0.0005763041,0.00001032507,0.02346629,0.00007053535,0.0001564958,0.00003233436,0.000125395,0.000005352879,0.9714874,0.00004865853,0.003644681,0.0003762556],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9933329,0.0002155719,0.0003801391,0.0003253896,0.00003520876,0.00009900897,0.0001726839,0.0001064161,0.005332692],"genre_scores_gemma":[0.9965337,0.0002498552,0.0005949267,0.00004765916,0.0001246822,0.00005826966,0.0003731197,0.00006735963,0.001950451],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0198955,"threshold_uncertainty_score":0.9998873,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009111517130839917,"score_gpt":0.2036006059535503,"score_spread":0.1944890888227103,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}