{"id":"W1988585008","doi":"10.1002/ejic.200801195","title":"Syntheses, Structures and Reactivities of Rhodium 4,5‐Diazafluorene Derivatives","year":2009,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Rhodium; Trifluoromethanesulfonate; Counterion; Catalysis; Olefin fiber; Medicinal chemistry; Chloride; Aqueous solution; Crystal structure; Nuclear magnetic resonance spectroscopy; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002299937,0.0003666523,0.0003469379,0.0002153211,0.0001499619,0.0002334945,0.0003883929,0.0002796735,0.00143021],"category_scores_gemma":[0.0002049656,0.0001496996,0.0002329454,0.0001850044,0.0001321903,0.0002063267,0.0001541789,0.0003515633,0.0006103012],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004886022,"about_ca_system_score_gemma":0.0001769418,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008854754,"about_ca_topic_score_gemma":0.001036822,"domain_scores_codex":[0.9998674,0.00002253845,0.00001385425,0.0000252217,0.00003459373,0.00003638185],"domain_scores_gemma":[0.9999279,0.00001393886,0.00001531886,0.00001338855,0.00001353041,0.00001578456],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008929874,0.00002928025,0.00006537149,0.0000900404,0.000008595703,0.00009134755,0.00003390756,0.0003230689,0.9957494,0.0002373966,0.0000842798,0.003198172],"study_design_scores_gemma":[0.00002451427,0.0002522955,0.0004126915,0.000004687206,0.00001489302,0.0001005697,0.000006867651,0.0002507154,0.9959996,0.00002080079,0.002901985,0.00001049475],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9789373,0.003291495,0.006239094,0.0001180995,0.00005267228,0.0001485348,0.000978093,0.000191786,0.01004296],"genre_scores_gemma":[0.9877375,0.001803521,0.005832149,0.00004042744,0.00001072911,0.00005765191,0.0006501074,0.00003575779,0.003832062],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00143021,"threshold_uncertainty_score":0.004784524,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009316372651398917,"score_gpt":0.2083295624687836,"score_spread":0.1990131898173847,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}