{"id":"W1988622442","doi":"10.1002/kin.10093","title":"Temperature‐dependent kinetic study for ozonolysis of selected tropospheric alkenes","year":2002,"lang":"en","type":"article","venue":"International Journal of Chemical Kinetics","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":69,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Ozonolysis; Isoprene; Alkene; Reaction rate constant; Arrhenius equation; Pentene; Propene; Ozone; Double bond; Heptene; Photochemistry; Physical chemistry; Organic chemistry; Kinetics; Activation energy; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003083731,0.0005021256,0.0003721987,0.0003434781,0.0001882871,0.0003286742,0.0003114262,0.0002982336,0.001133631],"category_scores_gemma":[0.0004794775,0.0002012483,0.0004229967,0.0002252103,0.0001611618,0.0004530611,0.0001517726,0.0004146856,0.0005175363],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000405807,"about_ca_system_score_gemma":0.0002147923,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002563935,"about_ca_topic_score_gemma":0.001498718,"domain_scores_codex":[0.9998534,0.00001433272,0.000007494352,0.00003993469,0.00005353605,0.00003128355],"domain_scores_gemma":[0.9997591,0.0000878159,0.00004618592,0.00001465177,0.00007449472,0.00001769472],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003355674,0.00006406254,0.004602391,0.0001985335,0.00004446989,0.00007958166,0.00004815005,0.002307897,0.9885915,0.0001873322,0.0001068375,0.003433847],"study_design_scores_gemma":[0.00001505526,0.0001947178,0.01436253,0.000008176608,0.00003378426,0.000112299,0.00003788184,0.01329064,0.9710553,0.00009874915,0.0007739476,0.00001686363],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.990214,0.001827351,0.005733983,0.00005118285,0.00002059334,0.00004839568,0.0008838832,0.00008612782,0.001134507],"genre_scores_gemma":[0.9964086,0.001055954,0.00113399,0.000008310307,0.000005583902,0.00001749623,0.0005521925,0.00001975902,0.0007980102],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002563935,"threshold_uncertainty_score":0.005098045,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01140036524183203,"score_gpt":0.2248989700388712,"score_spread":0.2134986047970392,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}