{"id":"W1988636692","doi":"10.1021/ja002738m","title":"O-Protonation of a Terminal Nitrosyl Group To Form an η<sup>1</sup>-Hydroxylimido Ligand","year":2001,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Protonation; Terminal (telecommunication); Ligand (biochemistry); Group (periodic table); Stereochemistry; Medicinal chemistry; Organic chemistry; Ion; Receptor; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004222963,0.0006565261,0.0004459468,0.0002413368,0.0004738044,0.0002247339,0.0009157036,0.0005115367,0.07176343],"category_scores_gemma":[0.0004681141,0.0002196047,0.0003913206,0.0002280135,0.0002835098,0.000795446,0.0006162557,0.001021047,0.01379241],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000409893,"about_ca_system_score_gemma":0.0008343255,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001240222,"about_ca_topic_score_gemma":0.001944565,"domain_scores_codex":[0.9996018,0.00002926808,0.00001552093,0.00006656858,0.00009689025,0.0001900458],"domain_scores_gemma":[0.9997547,0.00004594669,0.00004377508,0.0000495516,0.00004577341,0.00006027696],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.003559536,0.0004136269,0.00152166,0.002636828,0.0001226976,0.001924875,0.0007003897,0.00171406,0.7783081,0.01655452,0.1081215,0.08442219],"study_design_scores_gemma":[0.0003083234,0.002692068,0.002885039,0.0001796319,0.00007160367,0.001176981,0.0002573868,0.002627658,0.7578712,0.00170696,0.2300648,0.0001583916],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4772936,0.005028866,0.05595628,0.007389498,0.005414879,0.001045146,0.007945986,0.003318777,0.4366071],"genre_scores_gemma":[0.8285563,0.005843478,0.01034098,0.002017899,0.0005276298,0.0004984477,0.007001769,0.0006024296,0.1446111],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07176343,"threshold_uncertainty_score":0.2400725,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01369164768977633,"score_gpt":0.2630384328635028,"score_spread":0.2493467851737265,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}