{"id":"W1988719389","doi":"10.1002/chin.200705150","title":"Acids as Proline Co‐Catalysts in the Aldol Reaction of 1,3‐Dioxan‐5‐ones.","year":2007,"lang":"en","type":"article","venue":"ChemInform","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Chemistry; Aldol reaction; Proline; Catalysis; Organic chemistry; Combinatorial chemistry; Amino acid; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004486476,0.0001923262,0.0002156566,0.00005535171,0.0000514103,0.00001462295,0.0003679116,0.0002053208,0.0005469274],"category_scores_gemma":[0.000316131,0.0001566863,0.0000945119,0.0003578622,0.000125429,0.0001476652,0.00004739743,0.000389016,0.00008774632],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002212198,"about_ca_system_score_gemma":0.00009785204,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006508164,"about_ca_topic_score_gemma":0.00002170562,"domain_scores_codex":[0.9986231,4.520818e-7,0.0004964059,0.0002106247,0.0003620492,0.0003073776],"domain_scores_gemma":[0.9988229,0.0001646143,0.0002586298,0.0005890745,0.00009206735,0.0000726996],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006113938,0.0001419597,0.0009388685,0.000145885,0.00002741183,0.00001056468,0.001025984,8.452925e-8,0.9819078,0.0000469139,0.001754885,0.01393847],"study_design_scores_gemma":[0.0005450504,0.000009465897,0.001578159,0.00004658072,0.00002273337,0.0001457484,0.002457743,0.000002775371,0.9668636,0.00005437772,0.02811731,0.0001564999],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.459856,0.00002721688,0.000001366611,0.0001163238,0.0000253198,0.00007437421,0.00001229922,0.00003991095,0.5398472],"genre_scores_gemma":[0.991708,0.00001574058,0.00002660106,0.0000570081,0.0002043036,0.00002131538,0.000206138,0.00002066018,0.007740222],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.5321069,"threshold_uncertainty_score":0.638948,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01405972813180889,"score_gpt":0.280159381642591,"score_spread":0.2660996535107821,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}