{"id":"W1988743710","doi":"10.1021/ac030158c","title":"Quantitative Elemental Analysis for Rhodium and Palladium in Minerals by Time-of-Flight Resonance Ionization Mass Spectrometry","year":2003,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Mass spectrometry; Rhodium; Palladium; Elemental analysis; Quantitative analysis (chemistry); Ionization; Time-of-flight mass spectrometry; Analytical Chemistry (journal); Inorganic chemistry; Environmental chemistry; Chromatography; Organic chemistry; Catalysis; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006182227,0.0004890568,0.0003745851,0.0009423044,0.0003184167,0.0004102589,0.0004760664,0.0002375705,0.002331507],"category_scores_gemma":[0.0009218095,0.0001717626,0.0002982907,0.0003461084,0.0003145096,0.0003151372,0.0002258227,0.0002944065,0.0009971287],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000457857,"about_ca_system_score_gemma":0.0004603614,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003191787,"about_ca_topic_score_gemma":0.005945264,"domain_scores_codex":[0.9993023,0.00006653575,0.00004395581,0.0001185429,0.0004161913,0.00005247543],"domain_scores_gemma":[0.9995224,0.0001107612,0.00004739092,0.00005796797,0.0002405039,0.0000210134],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005496138,0.00001638307,0.0005645637,0.00005090426,0.00000941909,0.00002329985,0.00001464874,0.0001023252,0.9931239,0.0001113231,0.00007125212,0.005856984],"study_design_scores_gemma":[0.000005186806,0.00007186085,0.002743695,0.000003978372,0.00001385456,0.000165028,0.00001798482,0.001177002,0.9936888,0.00008772835,0.00201802,0.000006766832],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7226005,0.003865683,0.2525769,0.0002695946,0.0000654271,0.0004825571,0.004759388,0.001845789,0.01353404],"genre_scores_gemma":[0.7546189,0.002189952,0.2278055,0.00009916382,0.00001759604,0.0002195418,0.002767975,0.0002523628,0.012029],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003191787,"threshold_uncertainty_score":0.007799625,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01378946844476682,"score_gpt":0.2752764846752923,"score_spread":0.2614870162305255,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}