{"id":"W1988788779","doi":"10.1021/ic048443h","title":"A Zinc Carboxylate Network Containing Metal Sites with Low Coordination Numbers","year":2005,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University; Simon Fraser University; Western University","funders":"","keywords":"Chemistry; Bifunctional; Carboxylate; Zinc; Steric effects; Dimer; Metal; Linker; Coordination complex; Coordination geometry; Metal-organic framework; Stereochemistry; Polymer chemistry; Inorganic chemistry; Molecule; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001847353,0.0003605282,0.0003916341,0.00001461622,0.0002358803,0.0001001794,0.0004060155,0.0003235677,0.008503072],"category_scores_gemma":[0.0001235837,0.0003417747,0.0001175779,0.0003122032,0.0001181087,0.0001488931,0.0001000594,0.0005174124,0.0001483435],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002164012,"about_ca_system_score_gemma":0.0001277094,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002797011,"about_ca_topic_score_gemma":0.00002817321,"domain_scores_codex":[0.9980972,0.00001369477,0.0004438529,0.000573828,0.0003438647,0.0005275013],"domain_scores_gemma":[0.9985012,0.0001901608,0.0002855407,0.0007102614,0.000113188,0.0001996581],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003672477,0.0001318301,0.002078703,0.0001123606,0.0002077691,0.000008487636,0.0001719701,0.0002390158,0.9927805,0.0002839016,0.001366435,0.002582294],"study_design_scores_gemma":[0.000723852,0.00001033133,0.0001301927,0.0001682418,0.0001850294,0.00009399705,0.000305782,0.001467983,0.9799602,0.0002097265,0.01615467,0.0005899785],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9621491,0.0005444302,0.0004881339,0.0008103153,0.00002893869,0.00009681131,0.00002155499,0.0003048785,0.03555581],"genre_scores_gemma":[0.9925095,0.00002655907,0.001747069,0.0001644516,0.001074936,0.00006019132,0.0001141609,0.00008666349,0.00421642],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03133938,"threshold_uncertainty_score":0.9999034,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007517085234350443,"score_gpt":0.2166279683158201,"score_spread":0.2091108830814696,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}