{"id":"W1989118706","doi":"10.1126/science.1194237","title":"Direct Observation and Quantification of CO <sub>2</sub> Binding Within an Amine-Functionalized Nanoporous Solid","year":2010,"lang":"en","type":"article","venue":"Science","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":916,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa; University of Calgary","funders":"","keywords":"Amine gas treating; Sorbent; Sorption; Molecule; Nanoporous; Adsorption; Chemistry; Molecular binding; Binding energy; Physical chemistry; Computational chemistry; Materials science; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007897222,0.0000922105,0.0001295458,0.000069347,0.0002986878,0.00007903852,0.000254189,0.00008559809,0.0001534696],"category_scores_gemma":[0.0005567005,0.00008443181,0.00002211532,0.0004467714,0.0004529155,0.0003258012,0.00002929597,0.0001341293,0.00001414498],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000187859,"about_ca_system_score_gemma":0.0001071845,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001452791,"about_ca_topic_score_gemma":0.00002824239,"domain_scores_codex":[0.9988617,0.00001151417,0.0002705437,0.0003725306,0.0003342265,0.0001494753],"domain_scores_gemma":[0.9989727,0.0001087546,0.0002470793,0.0004345154,0.000149182,0.00008783301],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000004065121,0.00004956822,0.001920891,0.00001488308,0.000002779827,8.455501e-8,0.0001482606,0.000009910872,0.9908683,0.002177174,0.00001244144,0.004791596],"study_design_scores_gemma":[0.00007949098,0.000007655138,0.009588099,0.00002032712,0.0000109637,0.00000405877,0.0001054548,0.00250229,0.9868402,0.0004084752,0.000333242,0.00009966789],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979064,0.00002374803,0.0008803314,0.00009995571,0.0001348037,0.00006830785,0.00001573392,0.00004916588,0.0008214837],"genre_scores_gemma":[0.9969746,0.00001751211,0.002701836,0.00001936041,0.00005400352,0.00002311859,0.00002479086,0.000009773335,0.0001749953],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007667208,"threshold_uncertainty_score":0.344303,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03042000420441536,"score_gpt":0.2775643025466343,"score_spread":0.2471442983422189,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}