{"id":"W1989461498","doi":"10.1021/om000497l","title":"Ruthenium-Assisted Insertion of Isothiocyanates into the Silicon−Sulfur Bond:  A Comparative Study on the Reactivity of the S−Si and S−H Bonds in CpRu(PPh<sub>3</sub>)<sub>2</sub>SX (X = H, Si<i><sup>i</sup></i>Pr<sub>3</sub>) Complexes","year":2000,"lang":"en","type":"article","venue":"Organometallics","topic":"Ferrocene Chemistry and Applications","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Ruthenium; Medicinal chemistry; Isothiocyanate; Reactivity (psychology); Ligand (biochemistry); Nucleophile; Stereochemistry; Catalysis; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001668113,0.0003559545,0.0002828462,0.0001132332,0.0001277215,0.0002107842,0.000331134,0.0004296842,0.001277087],"category_scores_gemma":[0.0002216162,0.0001813493,0.0002024209,0.0001535906,0.0002288695,0.0002023769,0.0001881717,0.0004114065,0.0003268303],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002669409,"about_ca_system_score_gemma":0.0001867982,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009000697,"about_ca_topic_score_gemma":0.00168039,"domain_scores_codex":[0.9998504,0.00002700181,0.000007683687,0.0000299006,0.00003611299,0.00004888408],"domain_scores_gemma":[0.9998941,0.00002633359,0.0000304833,0.00001531204,0.00001687086,0.00001676888],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001768283,0.00002166793,0.00008245662,0.00009143136,0.00001437499,0.00006233526,0.00005502678,0.0002793289,0.9975522,0.000132294,0.00005351705,0.001478586],"study_design_scores_gemma":[0.00001514332,0.0002734013,0.0005257087,0.000003442454,0.000009320076,0.00004870677,0.00001433417,0.0004988805,0.9979335,0.000008756677,0.0006613674,0.000007476352],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961515,0.0006052774,0.0009890177,0.00003051252,0.00001232313,0.00002752917,0.00007176719,0.00004726922,0.002064745],"genre_scores_gemma":[0.9974582,0.0003854004,0.0007885866,0.00001942121,0.000003087622,0.00001142758,0.00007261902,0.00001684383,0.001244448],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001277087,"threshold_uncertainty_score":0.004272282,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02107978689421631,"score_gpt":0.2411525552538939,"score_spread":0.2200727683596776,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}