{"id":"W1989620573","doi":"10.1002/chin.200223222","title":"ChemInform Abstract: Synthesis of N‐Glycosides. An Alternative Approach Based on Diastereoselective Base Coupling and S<sub>N</sub>2 Cyclization.","year":2002,"lang":"en","type":"article","venue":"ChemInform","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Base (topology); Glycoside; Combinatorial chemistry; Coupling (piping); Organic chemistry; Stereochemistry; Mathematics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001443406,0.001255449,0.000425896,0.000505426,0.000342983,0.0004743105,0.0006133462,0.0003591844,0.0134091],"category_scores_gemma":[0.0001664021,0.0003054578,0.0004770658,0.0006418647,0.0001694616,0.0005639846,0.0004054267,0.0008846262,0.007175071],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004689224,"about_ca_system_score_gemma":0.001061574,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001128837,"about_ca_topic_score_gemma":0.001850682,"domain_scores_codex":[0.9998926,0.00001607019,0.0000076645,0.00002651878,0.00003080189,0.00002643384],"domain_scores_gemma":[0.9999591,0.0000034162,0.000006612852,0.000006881815,0.000006219088,0.00001782347],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009386467,0.00025175,0.0002816445,0.0007548415,0.0000869842,0.001151817,0.000124845,0.001748558,0.8212497,0.007911744,0.01629761,0.1492019],"study_design_scores_gemma":[0.0002465003,0.0007698254,0.001373637,0.00007182349,0.00007614921,0.001325629,0.00005031178,0.00189252,0.886425,0.00219406,0.1055207,0.00005373055],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.4395675,0.02124039,0.1610657,0.002840721,0.00493984,0.001536281,0.01608392,0.0044994,0.3482264],"genre_scores_gemma":[0.7459106,0.02868518,0.09000405,0.0012041,0.0005155561,0.0004313256,0.01166937,0.0008488207,0.120731],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0134091,"threshold_uncertainty_score":0.04485792,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02068308943021229,"score_gpt":0.2138914024919409,"score_spread":0.1932083130617286,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}