{"id":"W1989634615","doi":"10.1021/bm801411w","title":"Fatty Acid-Derived Diisocyanate and Biobased Polyurethane Produced from Vegetable Oil: Synthesis, Polymerization, and Characterization","year":2009,"lang":"en","type":"article","venue":"Biomacromolecules","topic":"Polymer composites and self-healing","field":"Materials Science","cited_by":260,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hexamethylene diisocyanate; Polyurethane; Polyol; Isophorone diisocyanate; Chemistry; Oleic acid; Fatty acid; Organic chemistry; Isocyanate; Toluene diisocyanate; Polymer chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001770607,0.0002735829,0.0001354389,0.0003183202,0.0001111174,0.0001977457,0.0001932922,0.0002530919,0.000487278],"category_scores_gemma":[0.0002393633,0.0001716067,0.0001483983,0.0002601539,0.0002203951,0.000267478,0.0002096501,0.000322305,0.0002209868],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001979706,"about_ca_system_score_gemma":0.0002343677,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003731627,"about_ca_topic_score_gemma":0.0007343234,"domain_scores_codex":[0.9998569,0.00001766233,0.000009433572,0.00003372948,0.00005694578,0.00002525128],"domain_scores_gemma":[0.9998692,0.00001993048,0.00003331379,0.00001369152,0.00003205935,0.0000318142],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002149274,0.000006525066,0.00007193653,0.00002307313,8.732181e-7,0.00002648084,0.00001140463,0.00004392178,0.9985533,0.00006602627,0.000003423045,0.001171498],"study_design_scores_gemma":[0.000002039278,0.00007644167,0.0004330325,0.000001364269,0.000002027616,0.00007046617,0.000007621001,0.0002818529,0.9983728,0.00001988993,0.0007301893,0.000002214921],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9731367,0.001888018,0.02282658,0.00005047285,0.00001795266,0.00006560946,0.00009617294,0.00005385427,0.00186455],"genre_scores_gemma":[0.9795048,0.0009912997,0.01629068,0.000023399,0.00000576545,0.00005328766,0.000238882,0.00002662015,0.002865411],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000487278,"threshold_uncertainty_score":0.001630068,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007623005376855582,"score_gpt":0.2109998850545196,"score_spread":0.203376879677664,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}