{"id":"W1989634615","doi":"10.1021/bm801411w","title":"Fatty Acid-Derived Diisocyanate and Biobased Polyurethane Produced from Vegetable Oil: Synthesis, Polymerization, and Characterization","year":2009,"lang":"en","type":"article","venue":"Biomacromolecules","topic":"Polymer composites and self-healing","field":"Materials Science","cited_by":260,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hexamethylene diisocyanate; Polyurethane; Polyol; Isophorone diisocyanate; Chemistry; Oleic acid; Fatty acid; Organic chemistry; Isocyanate; Toluene diisocyanate; Polymer chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001217498,0.0002485382,0.0002906268,0.00009666278,0.0002703343,0.0002627175,0.0001551861,0.0001048326,0.00004303834],"category_scores_gemma":[0.00005023564,0.0002302383,0.00003238823,0.0001854024,0.0001101261,0.0002638269,0.00005983785,0.00004756912,0.00001189907],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001836534,"about_ca_system_score_gemma":0.00003449471,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001933,"about_ca_topic_score_gemma":0.00000569324,"domain_scores_codex":[0.9984851,0.000116708,0.0002986195,0.0005580051,0.0001902484,0.0003513208],"domain_scores_gemma":[0.9993127,0.00004095295,0.0001670758,0.0002740132,0.00004361921,0.0001616683],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005717417,0.00004924817,0.0005455197,0.00001996278,0.00001152539,0.00001014303,0.0001871875,2.662841e-7,0.9864383,0.00007063556,0.000002492923,0.01260754],"study_design_scores_gemma":[0.0003243464,0.00005409843,0.0291962,0.00006900974,0.0000427337,0.00001382708,0.00001504597,0.0005627002,0.9693153,0.00007887421,0.00004943864,0.0002784439],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9912737,0.00338914,0.003579395,0.001093949,0.0001520026,0.0001153011,0.0001820782,0.0001670941,0.00004735358],"genre_scores_gemma":[0.9957237,0.0002809143,0.003213664,0.0004510454,0.0001032238,0.00001174525,0.0001740531,0.00002327481,0.00001833203],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02865068,"threshold_uncertainty_score":0.9388844,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007623005376855582,"score_gpt":0.2109998850545196,"score_spread":0.203376879677664,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}