{"id":"W1989699872","doi":"10.1002/chin.200451073","title":"Rhodium‐Catalyzed Heck‐Type Coupling of Boronic Acids with Activated Alkenes in an Aqueous Emulsion.","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Rhodium; Catalysis; Aqueous solution; Coupling (piping); Boronic acid; Emulsion; Heck reaction; Aqueous medium; Polymer chemistry; Organic chemistry; Palladium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00009269416,0.0002755473,0.0003630477,0.0001057721,0.00008935091,0.00005175676,0.0003288225,0.0002293034,0.0002232826],"category_scores_gemma":[0.0001126568,0.0002568596,0.00007148409,0.0004567594,0.0001924205,0.0004296534,0.00008283201,0.0003467207,0.00002485178],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005319202,"about_ca_system_score_gemma":0.0003144092,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005136327,"about_ca_topic_score_gemma":0.0002943734,"domain_scores_codex":[0.9984832,1.846593e-8,0.0004669701,0.00033859,0.0002970377,0.0004142221],"domain_scores_gemma":[0.9986472,0.0000651892,0.0002332644,0.0007233174,0.0001888319,0.0001422671],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002887509,0.0002184359,0.001251388,0.0001665156,0.00003808255,0.00001816503,0.0007970356,0.0009946113,0.9930376,0.00002498694,0.00001609883,0.003148273],"study_design_scores_gemma":[0.001970429,0.00004350062,0.0005645213,0.0002432615,0.00003436458,0.00006745213,0.0008968304,0.0003134125,0.9952804,0.00004606889,0.0002267671,0.0003129342],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9952543,0.0001427414,0.000001728444,0.00003145931,0.00005529705,0.000107411,0.00002137973,0.0001596993,0.004225931],"genre_scores_gemma":[0.9988227,0.00004113602,0.00005208,0.00001026595,0.00006605653,0.00002188568,0.000374331,0.00005055097,0.0005609579],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003664973,"threshold_uncertainty_score":0.9999884,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01378033467193218,"score_gpt":0.266765001131531,"score_spread":0.2529846664595988,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}