{"id":"W1989699872","doi":"10.1002/chin.200451073","title":"Rhodium‐Catalyzed Heck‐Type Coupling of Boronic Acids with Activated Alkenes in an Aqueous Emulsion.","year":2004,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Rhodium; Catalysis; Aqueous solution; Coupling (piping); Boronic acid; Emulsion; Heck reaction; Aqueous medium; Polymer chemistry; Organic chemistry; Palladium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003140509,0.0003916197,0.0002638509,0.0001931682,0.000154175,0.000260874,0.0003599142,0.0002968668,0.003613411],"category_scores_gemma":[0.0003172827,0.0002211175,0.0002213714,0.0001278046,0.0001784899,0.0005374521,0.0003274316,0.0006852608,0.001775592],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000276154,"about_ca_system_score_gemma":0.0003285235,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009641079,"about_ca_topic_score_gemma":0.001646037,"domain_scores_codex":[0.9998699,0.00002102114,0.00000660133,0.00002936605,0.00003313043,0.00004000839],"domain_scores_gemma":[0.9999557,0.00001319903,0.000008278098,0.000004962728,0.000007640388,0.00001033912],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001948164,0.00005664502,0.00004431692,0.0001796306,0.00002086602,0.0001947148,0.00004799869,0.0002071129,0.9911409,0.001030206,0.0004826895,0.006399994],"study_design_scores_gemma":[0.00005840369,0.0002204082,0.000204563,0.00001328378,0.00002710572,0.0001457309,0.00001596351,0.0005920953,0.9948571,0.0001665071,0.003689265,0.000009659368],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8543023,0.01053246,0.05553383,0.0006136746,0.0004642256,0.0003882064,0.0004915998,0.000780164,0.07689352],"genre_scores_gemma":[0.9740934,0.003731508,0.005277593,0.00008075963,0.00003783388,0.00003424761,0.0002295915,0.00006285357,0.0164522],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003613411,"threshold_uncertainty_score":0.01208806,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01378033467193218,"score_gpt":0.266765001131531,"score_spread":0.2529846664595988,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}