{"id":"W1989806773","doi":"10.1002/0471264180.or058.01","title":"Simmons‐Smith Cyclopropanation Reaction","year":2001,"lang":"en","type":"other","venue":"Organic reactions","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":81,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Cyclopropanation; Allylic rearrangement; Chemistry; Carbenoid; Double bond; Stereospecificity; Electrophile; Ether; Reagent; Chemoselectivity; Organic chemistry; Enantioselective synthesis; Medicinal chemistry; Stereochemistry; Catalysis; Rhodium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0000829468,0.0005890636,0.0004739848,0.000538283,0.0002159919,0.00008242533,0.0003105098,0.0009876085,0.06763319],"category_scores_gemma":[0.0001281896,0.0006358879,0.0002145478,0.0005578758,0.00006107718,0.0001643741,0.00006782129,0.0009364233,0.00453436],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009272627,"about_ca_system_score_gemma":0.0002499417,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001672416,"about_ca_topic_score_gemma":0.0006509384,"domain_scores_codex":[0.9975716,0.00003242954,0.0005061407,0.0008481338,0.0005703964,0.0004713292],"domain_scores_gemma":[0.9977367,0.00005407894,0.0007231046,0.001170317,0.0001112692,0.0002045429],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00001383726,0.0002336522,0.00004610551,0.0004146367,0.000256068,0.00004954928,0.00008211979,0.000001429062,0.720065,0.0005301616,0.2506185,0.02768892],"study_design_scores_gemma":[0.0003881011,0.00001559705,0.00002038459,0.000288308,0.000214262,0.0003307456,0.0006986303,0.000009884436,0.03102995,0.00009741378,0.9662921,0.0006145765],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.0002254065,0.0007068198,0.001459745,0.0001509165,0.001188913,0.000267716,0.00007085418,0.002524295,0.9934053],"genre_scores_gemma":[0.004281593,0.003339105,0.0006015608,0.00002798653,0.002090449,0.0001040825,0.0006410664,0.001549003,0.9873651],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.7156736,"threshold_uncertainty_score":0.9996092,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009680082430948657,"score_gpt":0.2296488026985318,"score_spread":0.2199687202675832,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}