{"id":"W1989806773","doi":"10.1002/0471264180.or058.01","title":"Simmons‐Smith Cyclopropanation Reaction","year":2001,"lang":"en","type":"other","venue":"Organic reactions","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":81,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Cyclopropanation; Allylic rearrangement; Chemistry; Carbenoid; Double bond; Stereospecificity; Electrophile; Ether; Reagent; Chemoselectivity; Organic chemistry; Enantioselective synthesis; Medicinal chemistry; Stereochemistry; Catalysis; Rhodium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001982677,0.0008326823,0.0002627997,0.0008281881,0.0004496085,0.0002514525,0.0003583331,0.0002744957,0.01310004],"category_scores_gemma":[0.0002055489,0.0001844093,0.0003066954,0.0004075902,0.0003324065,0.0004749944,0.0006654093,0.000953942,0.004108247],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005181454,"about_ca_system_score_gemma":0.0004973401,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008984503,"about_ca_topic_score_gemma":0.001047262,"domain_scores_codex":[0.9997386,0.00002826418,0.00001521129,0.00006744947,0.00006795553,0.00008246973],"domain_scores_gemma":[0.9999412,0.000009136832,0.000010793,0.000009737068,0.00001682663,0.00001218495],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0004217688,0.0002059742,0.0009692069,0.001294305,0.0001291146,0.001599629,0.0004938036,0.001576257,0.7312914,0.06507216,0.03514589,0.1618006],"study_design_scores_gemma":[0.00004680636,0.0004251131,0.0008669118,0.00005186148,0.00003546569,0.0007889438,0.0000515203,0.001238558,0.8186284,0.002786988,0.175038,0.00004150216],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"other","genre_gemma":"review","genre_scores_codex":[0.2885557,0.02356133,0.1061143,0.003821487,0.0037922,0.001182908,0.002820229,0.002997518,0.5671544],"genre_scores_gemma":[0.8610356,0.01115123,0.02143611,0.001014602,0.0003432959,0.0003494454,0.001472158,0.0001460425,0.1030515],"genre_candidate":"review","genre_consensus":null,"teacher_disagreement_score":0.01310004,"threshold_uncertainty_score":0.04382396,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009680082430948657,"score_gpt":0.2296488026985318,"score_spread":0.2199687202675832,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}