{"id":"W1989838380","doi":"10.1016/s1631-0748(02)01390-5","title":"Synthesis and structure of dimeric Rh-bis(tertiary phosphine) complexes, exceptionally useful synthetic precursors","year":2002,"lang":"en","type":"article","venue":"Comptes Rendus Chimie","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Rhodium; Toluene; Phosphine; Solvent; Dimer; Acetone; Catalysis; Medicinal chemistry; Nuclear magnetic resonance spectroscopy; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00007421721,0.0004536531,0.0007457415,0.0001524197,0.0001867251,0.00006685621,0.0005558369,0.0001761685,0.1630166],"category_scores_gemma":[0.0001565938,0.0004154379,0.0002615165,0.0002890873,0.0003711681,0.000131128,0.0002427897,0.0002698227,0.00007380344],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005641989,"about_ca_system_score_gemma":0.00001914108,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004327525,"about_ca_topic_score_gemma":0.00001129196,"domain_scores_codex":[0.997796,0.00005368303,0.0006183197,0.0006590667,0.000454857,0.000418081],"domain_scores_gemma":[0.9980244,0.0005294355,0.0003265312,0.0008467025,0.00006961981,0.0002032852],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006465448,0.0008214053,0.02585667,0.0007882144,0.001105977,0.00001911913,0.0006577808,0.00008167605,0.8409706,0.0005056841,0.00491013,0.1242181],"study_design_scores_gemma":[0.001759966,0.0001265784,0.1490401,0.001025463,0.001973212,0.000373909,0.0005793125,0.009043104,0.7490548,0.001610068,0.08229963,0.003113846],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9844328,0.008984561,0.00003828285,0.0002836307,0.00009902553,0.0000980562,0.0003233633,0.0001301436,0.005610208],"genre_scores_gemma":[0.9968387,0.0006781804,0.0005906459,0.000051591,0.0001174583,0.00001705811,0.00006249431,0.00006756957,0.001576257],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1629428,"threshold_uncertainty_score":0.9998298,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.015727483839025,"score_gpt":0.2023956913168325,"score_spread":0.1866682074778075,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}