{"id":"W1989908557","doi":"10.1016/j.ssnmr.2005.07.003","title":"Deuteron NMR spectra of ammonium ion isotopomers at low temperatures","year":2005,"lang":"en","type":"article","venue":"Solid State Nuclear Magnetic Resonance","topic":"Solid-state spectroscopy and crystallography","field":"Materials Science","cited_by":8,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of New Brunswick","funders":"","keywords":"Isotopomers; Deuterium; Ion; Chemistry; Ammonium perchlorate; Spectral line; Ammonium; NMR spectra database; Analytical Chemistry (journal); Physical chemistry; Atomic physics; Physics; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001745432,0.0002777904,0.0002383439,0.0002665264,0.0005451613,0.0002185884,0.0004513095,0.0004166229,0.005264357],"category_scores_gemma":[0.0002999342,0.0001423743,0.00009696309,0.0003645635,0.0005665122,0.0003880759,0.0001719697,0.0006814584,0.0006294991],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003503491,"about_ca_system_score_gemma":0.0001713602,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001139134,"about_ca_topic_score_gemma":0.001825928,"domain_scores_codex":[0.9998827,0.00001545971,0.000005206251,0.00002218746,0.00002982859,0.0000445589],"domain_scores_gemma":[0.999775,0.00009571631,0.00002622129,0.00002465693,0.00004617675,0.00003231062],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001376303,0.0000460326,0.0004385703,0.0001131204,0.00001484843,0.0001784164,0.0001328828,0.0003530928,0.9945595,0.0004513941,0.0005291629,0.001806841],"study_design_scores_gemma":[0.00005527811,0.0002191517,0.006051375,0.00001422633,0.00001823513,0.0001846206,0.0001349751,0.002148813,0.9883887,0.0002926039,0.002465783,0.00002619773],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9855046,0.0009148013,0.002510816,0.0002767413,0.0000590385,0.00000959928,0.0008375034,0.0001058079,0.009781033],"genre_scores_gemma":[0.9917121,0.0005731963,0.001060499,0.0001374954,0.0000199301,0.00001291269,0.00100353,0.00004146476,0.005438755],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005264357,"threshold_uncertainty_score":0.01761109,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004776714824076671,"score_gpt":0.2265166282427195,"score_spread":0.2217399134186429,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}