{"id":"W1989931489","doi":"10.1007/s10953-005-5113-x","title":"Ionization Constants of Aqueous Glycolic Acid at Temperatures up to 250 ∘C Using Hydrothermal pH Indicators and UV-Visible Spectroscopy","year":2005,"lang":"en","type":"article","venue":"Journal of Solution Chemistry","topic":"Chemical and Physical Properties in Aqueous Solutions","field":"Chemical Engineering","cited_by":16,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Guelph","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Glycolic acid; Aqueous solution; Ionization; Equilibrium constant; Hydrothermal circulation; Acid dissociation constant; Analytical Chemistry (journal); Spectroscopy; Partial molar property; Ultraviolet visible spectroscopy; Inorganic chemistry; Physical chemistry; Chromatography; Chemical engineering; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003026798,0.0004413892,0.00012248,0.0003952512,0.000145541,0.0002568156,0.0003827375,0.0002546731,0.002124837],"category_scores_gemma":[0.0004180974,0.0002072411,0.0001802535,0.0003606856,0.0002331783,0.0006700471,0.0002353908,0.0005137887,0.0004851833],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004702048,"about_ca_system_score_gemma":0.000206305,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001247007,"about_ca_topic_score_gemma":0.001324858,"domain_scores_codex":[0.9998474,0.00001224935,0.00001045197,0.00003939399,0.000050722,0.00003970258],"domain_scores_gemma":[0.9997835,0.00009352597,0.00005488244,0.0000122399,0.00003662103,0.00001943082],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009145618,0.000005071596,0.0001159352,0.00002745989,0.000002621237,0.00001260756,0.00002839894,0.00007902819,0.9980465,0.00008168563,0.0000364609,0.00147265],"study_design_scores_gemma":[0.000003072186,0.00003337317,0.0007870767,0.000002520062,0.000003648827,0.00002208901,0.00001050578,0.0003393758,0.9983611,0.00002882228,0.0004042442,0.000004224696],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9821743,0.002486989,0.01138408,0.00009688631,0.00003096445,0.00002629832,0.0005869297,0.0001173709,0.003096134],"genre_scores_gemma":[0.9898831,0.001847479,0.004567891,0.00004078652,0.000009236385,0.00002449144,0.0005715729,0.0000364905,0.00301887],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002124837,"threshold_uncertainty_score":0.007108331,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01026939333681529,"score_gpt":0.2461337307658633,"score_spread":0.235864337429048,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}