{"id":"W1990175613","doi":"10.1002/1099-1395(200008)13:8<461::aid-poc257>3.0.co;2-1","title":"Flash photolysis of 4-diazoisochroman-3-one in aqueous solution. Hydration of the carbene produced by loss of nitrogen and ketonization of the enol hydration product","year":2000,"lang":"en","type":"article","venue":"Journal of Physical Organic Chemistry","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; National Institutes of Health","keywords":"Chemistry; Enol; Aqueous solution; Flash photolysis; Carbene; Catalysis; Tautomer; Photochemistry; Nitrogen; Solvent; Keto–enol tautomerism; Organic chemistry; Kinetics; Reaction rate constant","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001479844,0.0004105984,0.0001827433,0.0001820985,0.0001858706,0.0001736746,0.0002003996,0.000270636,0.002741044],"category_scores_gemma":[0.0001241585,0.0001191625,0.0001545865,0.0001617511,0.0002617003,0.0002621538,0.000177925,0.0005281944,0.0004395967],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000484476,"about_ca_system_score_gemma":0.0002174142,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001590509,"about_ca_topic_score_gemma":0.001863369,"domain_scores_codex":[0.9999235,0.000006089423,0.000002209552,0.00002396618,0.00001984091,0.00002441809],"domain_scores_gemma":[0.9999442,0.00001802229,0.00001404574,0.000004766646,0.000006889501,0.00001196559],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005832369,0.000004721005,0.00003545752,0.000039831,0.000003575551,0.00007035844,0.00002237628,0.00004605809,0.9988239,0.00009107864,0.00004105529,0.0007630843],"study_design_scores_gemma":[0.00000971293,0.00008499555,0.0004609233,0.000003767314,0.000003638814,0.00007353675,0.00001462615,0.0002486303,0.9983199,0.00004701359,0.0007299263,0.00000316304],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9830863,0.001882612,0.004351532,0.0001211266,0.00007496362,0.00007520909,0.000257165,0.0001067486,0.01004428],"genre_scores_gemma":[0.9916265,0.001460027,0.001565,0.00003880732,0.00001159461,0.00003033958,0.0002799627,0.00002033621,0.004967474],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002741044,"threshold_uncertainty_score":0.009169698,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003134212318765895,"score_gpt":0.1836365526826703,"score_spread":0.1805023403639044,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}