{"id":"W1990235323","doi":"10.1021/jp0665224","title":"Origins of the High Thermal Stability of Alkylidene Groups on the Surface of β-Mo<sub>2</sub>C","year":2007,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Catalysis and Hydrodesulfurization Studies","field":"Engineering","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Bond cleavage; Carbide; Chemistry; Reactivity (psychology); Thermal stability; Surface modification; Carbon fibers; Desorption; Carbyne; Thermal desorption; Inert; Dissociation (chemistry); Oxygen; Chemical engineering; Adsorption; Materials science; Physical chemistry; Organic chemistry; Catalysis; Composite material; Composite number","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006652204,0.0001173327,0.0003245382,0.000008288336,0.00004623056,0.00000385522,0.0003523368,0.00003213573,0.00001310637],"category_scores_gemma":[0.00007607014,0.0000549763,0.0002315141,0.0002248903,0.0002202017,0.00003824789,0.00005835266,0.0002592619,7.774958e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006993771,"about_ca_system_score_gemma":0.00001816487,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001000534,"about_ca_topic_score_gemma":0.0000019701,"domain_scores_codex":[0.9989328,0.00003420281,0.0004432816,0.00005524063,0.0004124668,0.0001219422],"domain_scores_gemma":[0.9986224,0.0005242456,0.0003464813,0.00030222,0.000175242,0.00002947894],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005395382,0.0001141544,0.0001723311,0.00007005505,0.0001517196,2.244283e-7,0.0005896577,0.02513424,0.9732767,0.0002800745,0.00003561698,0.0001213242],"study_design_scores_gemma":[0.0001745427,0.00002700124,0.005531512,0.00004639593,0.0001017078,0.000001951714,0.000251491,0.000591474,0.9929976,0.0001991478,0.00002481114,0.00005237461],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9991606,0.000106521,0.0001013665,0.0001228967,0.00003581674,0.00004922643,0.00001982225,0.000005616056,0.0003980881],"genre_scores_gemma":[0.9997783,0.00003363302,0.000004938164,0.00000741755,0.0001601697,2.713225e-7,5.418124e-7,0.0000112476,0.000003501304],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02454277,"threshold_uncertainty_score":0.2241869,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009088091579327955,"score_gpt":0.2078772350258735,"score_spread":0.1987891434465456,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}