{"id":"W1990496174","doi":"10.1139/v11-112","title":"Introduction of C(5/6) side chains onto 2-azabicyclo[2.1.1]hexanes via a 6-anti-bromo-5-anti-hydroxy derivative","year":2011,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"American Chemical Society Petroleum Research Fund; National Science Foundation","keywords":"Chemistry; Ketone; Substituent; Nucleophile; Alkyl; Alcohol; Hexane; Selectivity; Aryl; Derivative (finance); Side chain; Medicinal chemistry; Bromine; Nitrogen atom; Organic chemistry; Catalysis; Polymer","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002791834,0.0004657081,0.0007729559,0.0001369259,0.0001847071,0.00004012482,0.0007815665,0.000380954,0.01081831],"category_scores_gemma":[0.0006232178,0.0005003897,0.000364573,0.0004163591,0.0005327338,0.0002907492,0.00005009073,0.0008910453,0.00002372376],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006185076,"about_ca_system_score_gemma":0.001686884,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002361626,"about_ca_topic_score_gemma":0.0009128184,"domain_scores_codex":[0.9973003,0.00002887362,0.001139842,0.0004488293,0.000419253,0.0006628924],"domain_scores_gemma":[0.9960853,0.0000830748,0.001287476,0.0007380482,0.0007558333,0.001050219],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000338678,0.00012375,0.004410078,0.0003205627,0.0003241038,0.0001627487,0.001252389,0.00001823477,0.9897316,0.00001645031,0.003106003,0.0005001746],"study_design_scores_gemma":[0.0006824081,0.00003043364,0.001110632,0.000174506,0.0001466101,0.001628351,0.001281113,0.00001771766,0.9791312,0.0002072027,0.01515053,0.0004393113],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9569696,0.0004019359,0.0002315102,0.0005671629,0.0002766301,0.00006141555,0.0001162492,0.00003047543,0.04134501],"genre_scores_gemma":[0.9946631,0.00004119875,0.0005936438,0.00004613432,0.001639899,0.000005694882,0.00004581099,0.00008035642,0.002884227],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03846078,"threshold_uncertainty_score":0.9997448,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01233141212813453,"score_gpt":0.1966032257743599,"score_spread":0.1842718136462254,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}