{"id":"W1990582481","doi":"10.1139/v05-060","title":"Oxidation of anisoles to <i>p</i>-benzoquinone monoketals catalyzed by a ruthenium complex of 1,4,7-trimethyl-1,4,7-triazacyclononane with <i>tert</i>-butyl hydroperoxide","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"University of Hong Kong; Research Grants Council, University Grants Committee","keywords":"Chemistry; Catalysis; Ruthenium; tert-Butyl hydroperoxide; Regioselectivity; Yield (engineering); Substrate (aquarium); Medicinal chemistry; Benzoquinone; Photochemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002770442,0.0004224863,0.0008663979,0.0001274594,0.00009789967,0.0000420914,0.0007987519,0.0002549884,0.002625375],"category_scores_gemma":[0.000254681,0.0004104467,0.000233435,0.000445698,0.0003200344,0.0002189587,0.00004572239,0.0004512074,0.00001090009],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004635768,"about_ca_system_score_gemma":0.001586201,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001484488,"about_ca_topic_score_gemma":0.0007259972,"domain_scores_codex":[0.9973062,0.00002548991,0.001272748,0.0003674235,0.0004950409,0.0005330492],"domain_scores_gemma":[0.9961404,0.0001434938,0.00127495,0.0006682196,0.0006623199,0.001110603],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001626206,0.0001337123,0.000952964,0.0002643923,0.0002394356,0.00002837252,0.0003787032,0.00009573244,0.9939881,0.00000201071,0.003208338,0.000545616],"study_design_scores_gemma":[0.001614444,0.00004959407,0.0000885205,0.0002996751,0.0001512111,0.0004466563,0.0006509022,0.00001901578,0.985369,0.00001377356,0.01091273,0.0003844327],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9917657,0.0006479933,0.0002311017,0.0008013545,0.00003293074,0.00009837357,0.0005427193,0.00001685022,0.005862985],"genre_scores_gemma":[0.9958945,0.00002765165,0.00235368,0.00006555908,0.0002784852,0.000006094006,0.0001467577,0.00007524239,0.001152051],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008619057,"threshold_uncertainty_score":0.9998347,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009597214511084999,"score_gpt":0.2133988813955062,"score_spread":0.2038016668844212,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}