{"id":"W1990582481","doi":"10.1139/v05-060","title":"Oxidation of anisoles to <i>p</i>-benzoquinone monoketals catalyzed by a ruthenium complex of 1,4,7-trimethyl-1,4,7-triazacyclononane with <i>tert</i>-butyl hydroperoxide","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"University of Hong Kong; Research Grants Council, University Grants Committee","keywords":"Chemistry; Catalysis; Ruthenium; tert-Butyl hydroperoxide; Regioselectivity; Yield (engineering); Substrate (aquarium); Medicinal chemistry; Benzoquinone; Photochemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001726471,0.0004451469,0.0002349462,0.0001197668,0.0001683082,0.0001377779,0.0003323136,0.0002445101,0.001002225],"category_scores_gemma":[0.0001571765,0.0001576869,0.0002153026,0.0001120853,0.0001947725,0.0002511985,0.0002102099,0.000452983,0.0003134978],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002428665,"about_ca_system_score_gemma":0.0001711586,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003110034,"about_ca_topic_score_gemma":0.000947322,"domain_scores_codex":[0.9998087,0.00003678164,0.00001520425,0.00004438833,0.00004647112,0.00004836879],"domain_scores_gemma":[0.9999021,0.00001916195,0.00003308777,0.00001573717,0.00001639693,0.00001337111],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002726079,0.000009262122,0.00002730521,0.00004947736,0.00000323711,0.00003684743,0.00002077209,0.00006677402,0.9985947,0.0001387528,0.00003220484,0.0009934572],"study_design_scores_gemma":[0.000004022042,0.0000961592,0.0001404114,0.000001530017,0.000003915593,0.00005653701,0.000007687452,0.0001032562,0.998717,0.00002769964,0.0008397399,0.00000214033],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9483948,0.001963634,0.04215222,0.000249022,0.0001321733,0.0002174842,0.0002746999,0.0002614688,0.006354551],"genre_scores_gemma":[0.9872988,0.0009909647,0.007704614,0.00003263593,0.00001154636,0.00005393198,0.000208047,0.0000331946,0.003666378],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001002225,"threshold_uncertainty_score":0.003352761,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009597214511084999,"score_gpt":0.2133988813955062,"score_spread":0.2038016668844212,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}