{"id":"W1990702952","doi":"10.1002/ejic.201100553","title":"Synthesis, Structure, and C–C Cross‐Coupling Activity of (Amine)bis(phenolato)iron(acac) Complexes","year":2011,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Chemistry; Methylene; Medicinal chemistry; Ligand (biochemistry); Alkyl; Amine gas treating; Halide; Aryl; Crystal structure; Reagent; Coupling reaction; Stereochemistry; Crystallography; Catalysis; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006165658,0.0003223837,0.0005101085,0.00005832075,0.0001059923,0.00005436529,0.0006801501,0.0001018565,0.005213491],"category_scores_gemma":[0.0005769242,0.0003018274,0.0001571428,0.0001375144,0.0001925212,0.0002336313,0.0002356144,0.0005842036,0.000007687372],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006775755,"about_ca_system_score_gemma":0.0001096179,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005141701,"about_ca_topic_score_gemma":5.347464e-7,"domain_scores_codex":[0.9980137,0.00005000827,0.0008968571,0.0003103415,0.0004474205,0.0002816483],"domain_scores_gemma":[0.9974753,0.000129434,0.001362703,0.0004979931,0.0002894554,0.0002450809],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001026251,0.00009323072,0.001524591,0.0004014905,0.0001290581,0.00007569847,0.0002710142,0.000009124544,0.9964043,0.00002001931,0.00003683799,0.0009319628],"study_design_scores_gemma":[0.0007412701,0.00002218823,0.004675561,0.000149799,0.0001135904,0.0005499207,0.0001689054,0.00004468797,0.9930509,0.00007879258,0.0001349604,0.0002694297],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910712,0.0004512263,0.0004013973,0.00001147349,0.00009434229,0.00002963274,0.00007483664,0.00003167065,0.007834184],"genre_scores_gemma":[0.9971522,0.0000640643,0.002145408,0.00001121089,0.0002754305,3.343621e-7,0.000006651132,0.00008318524,0.0002615003],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007572684,"threshold_uncertainty_score":0.9999434,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02404304419264593,"score_gpt":0.2271539968402653,"score_spread":0.2031109526476194,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}