{"id":"W1990839534","doi":"10.1021/ol034672g","title":"Hypervalent Iodine(III) Reagents as Safe Alternatives to α-Nitro-α-diazocarbonyls","year":2003,"lang":"en","type":"article","venue":"Organic Letters","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":83,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Cyclopropanation; Hypervalent molecule; Chemistry; Reactivity (psychology); Alkene; Reagent; Nitro; Iodine; Solvent; Medicinal chemistry; Organic chemistry; Combinatorial chemistry; Photochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002973636,0.0004405504,0.0001840315,0.0003483196,0.0001806026,0.0004550057,0.0008089268,0.0003943541,0.001749324],"category_scores_gemma":[0.0003305394,0.0001971078,0.0001718032,0.0001719487,0.0004549365,0.0004527092,0.0003607862,0.0004980789,0.0005983473],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000430664,"about_ca_system_score_gemma":0.0001945583,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002987928,"about_ca_topic_score_gemma":0.0003661137,"domain_scores_codex":[0.9998048,0.00004368477,0.0000110322,0.00003076153,0.00006068564,0.00004905656],"domain_scores_gemma":[0.9998531,0.00004261798,0.00004722592,0.00002006577,0.00001690212,0.0000200834],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002567408,0.00001668658,0.0001314355,0.0001665525,0.00001169316,0.0003131959,0.00005178475,0.000327963,0.9829823,0.006998142,0.0003267685,0.008416741],"study_design_scores_gemma":[0.00001313324,0.0001404865,0.0001188777,0.000008647263,0.0000144846,0.0002075155,0.00001709388,0.000241569,0.9925542,0.000383119,0.00629527,0.000005544539],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8655398,0.03278401,0.05456143,0.0006768791,0.0003643238,0.0001192968,0.0002751377,0.001053533,0.04462555],"genre_scores_gemma":[0.9824203,0.004420935,0.006661317,0.00009496351,0.000032556,0.00003459067,0.0001413756,0.00007159954,0.006122336],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001749324,"threshold_uncertainty_score":0.005852103,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01170184803314389,"score_gpt":0.2309457793519164,"score_spread":0.2192439313187725,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}