{"id":"W1991052573","doi":"10.1107/s1600536808020412","title":"<i>P</i>,<i>P</i>-Diphenyl-<i>N</i>-(1,1,2,2-tetraphenyl-1λ<sup>5</sup>-diphosphanylidene)phosphinous amide","year":2008,"lang":"he","type":"article","venue":"Acta Crystallographica Section E Structure Reports Online","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Sandia National Laboratories; U.S. Department of Energy; Laboratory Directed Research and Development; Division of Chemistry; Natural Sciences and Engineering Research Council of Canada; National Science Foundation","keywords":"Amide; Chemistry; Amine gas treating; Tetra; Crystallography; Crystal structure; Tris; Tetrahedral molecular geometry; Stereochemistry; Nuclear magnetic resonance spectroscopy; Trigonal crystal system; X-ray crystallography; Diffraction; Medicinal chemistry; Organic chemistry; Physics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004073609,0.000190149,0.00009097219,0.00008039162,0.0001162823,0.0001911375,0.0002251463,0.00013472,0.002904884],"category_scores_gemma":[0.0001004229,0.00008502887,0.00006003688,0.00008974102,0.0001839252,0.0002482805,0.0001251509,0.0001939114,0.0009013184],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001481065,"about_ca_system_score_gemma":0.0001698104,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003199244,"about_ca_topic_score_gemma":0.0003126617,"domain_scores_codex":[0.9999686,0.000003308812,0.000001679364,0.00001114235,0.000006522696,0.000008683457],"domain_scores_gemma":[0.9999663,0.000004385268,0.00001036626,0.000004614426,0.000004319559,0.00001008795],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001503897,0.000007894848,0.0001535977,0.0001005904,0.000003748245,0.0001516742,0.00001601619,0.0001280694,0.9939908,0.0007976621,0.0002551113,0.004244484],"study_design_scores_gemma":[0.0000183301,0.0002531367,0.001173147,0.000005301278,0.000008982508,0.000809509,0.00002650224,0.0004545204,0.9881285,0.0002814851,0.00883521,0.000005322072],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9460561,0.002308307,0.01125208,0.0001744168,0.000110067,0.00004739991,0.001142755,0.0003963953,0.03851249],"genre_scores_gemma":[0.9909235,0.0007332329,0.003310872,0.00004811836,0.00001363218,0.00001708996,0.0004763768,0.00004051999,0.004436726],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002904884,"threshold_uncertainty_score":0.009717822,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009220030181605802,"score_gpt":0.2138232916172703,"score_spread":0.2046032614356645,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}