{"id":"W1991063064","doi":"10.1021/ma049072r","title":"Rheological Monitoring of Polyacrylamide Gelation:  Importance of Cross-Link Density and Temperature","year":2004,"lang":"en","type":"article","venue":"Macromolecules","topic":"Hydrogels: synthesis, properties, applications","field":"Biochemistry, Genetics and Molecular Biology","cited_by":263,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Polymerization; Rheology; Polyacrylamide; Materials science; Viscoelasticity; Self-healing hydrogels; Acrylamide; Polymer chemistry; Polymer; Radical polymerization; Rheometer; Monomer; Shear modulus; Elastic modulus; Composite material","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001165204,0.0001273649,0.0001735229,0.00002486019,0.00007215489,0.00001514712,0.0001463717,0.000180944,0.000005868234],"category_scores_gemma":[0.0001239075,0.0001144662,0.00006274375,0.00007711076,0.0003133783,0.000005440159,0.0001095687,0.00008045667,0.000001666232],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001161349,"about_ca_system_score_gemma":0.00004859793,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003390399,"about_ca_topic_score_gemma":0.00001246249,"domain_scores_codex":[0.9991566,0.00002702836,0.0002721757,0.0002848421,0.0001098252,0.0001495221],"domain_scores_gemma":[0.9993623,0.000009430181,0.0001263814,0.0003299281,0.0001195932,0.00005237796],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002863504,0.00003184271,0.1447276,0.00002387412,0.00002597882,0.000002867485,0.00003660995,0.00007702689,0.8541231,0.0005473084,0.000002891866,0.0003723617],"study_design_scores_gemma":[0.0002248922,0.00006714397,0.1509187,0.00002037835,0.0000116832,0.0000237349,0.00002588691,0.000003619119,0.8479539,0.0005546095,0.00009452231,0.0001009497],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9970949,0.001915773,0.0004399797,0.0001741579,0.0000293101,0.0001318443,0.00001661791,0.00001219177,0.0001852537],"genre_scores_gemma":[0.9956536,0.0001697242,0.003949851,0.00003497236,0.00009048925,0.00001181448,0.0000204475,0.00001457596,0.0000545372],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006191131,"threshold_uncertainty_score":0.4667796,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0132288327475768,"score_gpt":0.2593622247063108,"score_spread":0.246133391958734,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}