{"id":"W1991324731","doi":"10.1002/kin.20157","title":"Experimental and kinetic study of shock initiated ignition in homogeneous methane–hydrogen–air mixtures at engine‐relevant conditions","year":2006,"lang":"en","type":"article","venue":"International Journal of Chemical Kinetics","topic":"Advanced Combustion Engine Technologies","field":"Chemical Engineering","cited_by":87,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Hydrogen; Shock tube; Methane; Ignition system; Stoichiometry; Branching (polymer chemistry); Thermodynamics; Mole fraction; Analytical Chemistry (journal); Organic chemistry; Physical chemistry; Shock wave","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003238895,0.0004232143,0.0005285824,0.0004022857,0.0003805301,0.0003186505,0.0004099935,0.0003628869,0.001206015],"category_scores_gemma":[0.0005785716,0.0002273833,0.0002258856,0.0005022422,0.0003745669,0.000341804,0.000315292,0.0004940724,0.0001560326],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005537663,"about_ca_system_score_gemma":0.000236023,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001810901,"about_ca_topic_score_gemma":0.001191795,"domain_scores_codex":[0.9997286,0.00003357954,0.00001819988,0.00004942977,0.0001084958,0.00006169659],"domain_scores_gemma":[0.99976,0.00009454889,0.0000394921,0.00002130049,0.00005785079,0.00002687124],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000835287,0.00006482186,0.001790625,0.0001121664,0.0000255679,0.0001153295,0.0001084409,0.001320315,0.9936138,0.0001447761,0.00003359914,0.001835225],"study_design_scores_gemma":[0.00002142788,0.0003385326,0.003975752,0.000002876588,0.00001121401,0.00004211748,0.00003185258,0.003877533,0.9914375,0.00002704474,0.0002260706,0.000008118802],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9974203,0.0002590703,0.001710608,0.00001539827,0.00000740849,0.00002001166,0.0001571957,0.00003637792,0.0003736416],"genre_scores_gemma":[0.998779,0.000131492,0.0007234681,0.000005104502,0.000003471363,0.00001008618,0.0001195008,0.000007798288,0.0002201703],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001810901,"threshold_uncertainty_score":0.004034519,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01341709687589313,"score_gpt":0.276661214428771,"score_spread":0.2632441175528778,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}