{"id":"W1991415240","doi":"10.1002/chin.201025049","title":"ChemInform Abstract: The First Cobalt‐Catalyzed Transformation of Alkynyl C—H Bond: Aldehyde—Alkyne—Amine (A<sup>3</sup>) Coupling.","year":2010,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Alkyne; Aldehyde; Amine gas treating; Catalysis; Transformation (genetics); Bond; Coupling (piping); Combinatorial chemistry; Cobalt; Polymer chemistry; Medicinal chemistry; Organic chemistry; Business; Metallurgy; Finance","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0008365698,0.0004801707,0.0005104793,0.0001188195,0.0002930917,0.00009984103,0.0008249719,0.0004937347,0.01003177],"category_scores_gemma":[0.0006499097,0.0003981913,0.0003371307,0.0004773938,0.0004175899,0.000681788,0.0001284576,0.0007664464,0.0001548156],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001642289,"about_ca_system_score_gemma":0.0002554966,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001012151,"about_ca_topic_score_gemma":0.00005701907,"domain_scores_codex":[0.9968631,7.945036e-8,0.001347493,0.0003662968,0.0008731958,0.0005498907],"domain_scores_gemma":[0.9970142,0.000530628,0.0006500037,0.001158486,0.0004259914,0.0002207511],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001024278,0.0009610545,0.0009166544,0.006012912,0.000869286,0.00001314466,0.02200975,0.0005621,0.2951307,0.008935656,0.1825293,0.4810351],"study_design_scores_gemma":[0.001386478,0.00001024362,0.0002503082,0.00007337444,0.00009985917,0.00006929451,0.001058604,0.003090788,0.6787611,0.0001291695,0.3146606,0.0004101286],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.1088774,0.0001244518,0.00003683838,0.001014468,0.0003451507,0.0004447952,0.0002841809,0.0002914635,0.8885812],"genre_scores_gemma":[0.9733,0.00009193793,0.0003380501,0.000356105,0.0007317496,0.0001869913,0.002837839,0.0001022443,0.02205512],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.8665261,"threshold_uncertainty_score":0.999847,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01381876956785722,"score_gpt":0.2548113784263783,"score_spread":0.2409926088585211,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}