{"id":"W1991415240","doi":"10.1002/chin.201025049","title":"ChemInform Abstract: The First Cobalt‐Catalyzed Transformation of Alkynyl C—H Bond: Aldehyde—Alkyne—Amine (A<sup>3</sup>) Coupling.","year":2010,"lang":"en","type":"article","venue":"ChemInform","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Alkyne; Aldehyde; Amine gas treating; Catalysis; Transformation (genetics); Bond; Coupling (piping); Combinatorial chemistry; Cobalt; Polymer chemistry; Medicinal chemistry; Organic chemistry; Business; Metallurgy; Finance","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001728715,0.0006146228,0.0002836772,0.0002587383,0.000445909,0.0004637935,0.0006543648,0.0004489979,0.01001002],"category_scores_gemma":[0.0002206522,0.0002174439,0.0002883155,0.0003388126,0.0003787077,0.0005576398,0.0005303513,0.0008746702,0.004686436],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004961262,"about_ca_system_score_gemma":0.0008200345,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001730074,"about_ca_topic_score_gemma":0.002413735,"domain_scores_codex":[0.9998066,0.00001859322,0.000009895742,0.00004935048,0.00004964291,0.00006592467],"domain_scores_gemma":[0.9999204,0.00001156975,0.00001397739,0.00001383105,0.00001411227,0.00002620278],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008737316,0.000220506,0.0005161879,0.001426498,0.0001127239,0.0008842337,0.0002748918,0.000875692,0.8182124,0.01458385,0.0352179,0.1268012],"study_design_scores_gemma":[0.00005854055,0.0005650593,0.001069037,0.0000351211,0.00004469853,0.000592806,0.00005084733,0.0009695762,0.8831483,0.0009816163,0.1124527,0.00003160117],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5559277,0.0230832,0.1685904,0.002144487,0.005624073,0.0008018442,0.005826038,0.006868303,0.231134],"genre_scores_gemma":[0.906132,0.008302713,0.020723,0.0004639331,0.0002466803,0.0001208683,0.00194673,0.0005225989,0.06154149],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01001002,"threshold_uncertainty_score":0.03348678,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01381876956785722,"score_gpt":0.2548113784263783,"score_spread":0.2409926088585211,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}