{"id":"W1991688817","doi":"10.1063/1.481557","title":"Noble gas–metal chemical bonding? The microwave spectra, structures, and hyperfine constants of Ar–CuX(X=F, Cl, Br)","year":2000,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":183,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Hyperfine structure; Bond-dissociation energy; Ab initio quantum chemistry methods; Ab initio; Quadrupole; Argon; Rotational spectroscopy; Spectral line; Atomic physics; Physical chemistry; Analytical Chemistry (journal); Dissociation (chemistry); Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001749303,0.0002619714,0.0004677154,0.00001203267,0.00007596385,0.00003110099,0.0005548809,0.0001507472,0.0006278703],"category_scores_gemma":[0.00004842674,0.0001507728,0.0002167971,0.0001223762,0.0005846967,0.00007791909,0.0000694328,0.0009930328,0.000002472569],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004597251,"about_ca_system_score_gemma":0.00007247819,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007271262,"about_ca_topic_score_gemma":3.87648e-7,"domain_scores_codex":[0.998507,0.00003696882,0.0005207643,0.0001608036,0.000456222,0.0003182843],"domain_scores_gemma":[0.9988635,0.0001725256,0.0003755243,0.0003755403,0.0000896595,0.0001233044],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003964638,0.00005585816,0.00004997971,0.00004610021,0.0001551595,0.00001255372,0.0002778588,0.000009811185,0.9943125,0.001731548,0.0008961804,0.002055986],"study_design_scores_gemma":[0.0007645586,0.0000347433,0.00001466436,0.00005381289,0.000211179,0.0006910406,0.0000517296,0.00005728346,0.9560559,0.04076249,0.001146036,0.0001565601],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.991529,0.001404089,0.00005629817,0.000460405,0.00004678562,0.00005108964,0.00002964042,0.000009189128,0.006413497],"genre_scores_gemma":[0.9982174,0.0002012574,0.0006416538,0.0001657044,0.0006146187,4.903945e-7,0.000005389732,0.00002729811,0.0001261557],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03903094,"threshold_uncertainty_score":0.687474,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005784682584783238,"score_gpt":0.2201337189238864,"score_spread":0.2143490363391032,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}