{"id":"W1991695554","doi":"10.1021/jo071102b","title":"Deoxygenative [1,2]-Hydride Shift Rearrangements in Nucleoside and Sugar Chemistry:  Analogy with the [1,2]-Electron Shift in the Deoxygenation of Ribonucleotides by Ribonucleotide Reductases<sup>1</sup>","year":2007,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Hydride; Deoxygenation; Stereochemistry; Furanose; Pyranose; Nucleoside; Deoxyadenosine; Ribonucleoside; Medicinal chemistry; Hydrogen; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001124653,0.0002595341,0.0001184267,0.00007591323,0.0001478643,0.0001630385,0.0002623121,0.0002369656,0.001268091],"category_scores_gemma":[0.00009814646,0.00009977463,0.0001483912,0.00008265583,0.0004196791,0.0002551414,0.0002450274,0.0004335867,0.0003070362],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002163441,"about_ca_system_score_gemma":0.000172878,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002350717,"about_ca_topic_score_gemma":0.0003836818,"domain_scores_codex":[0.9999379,0.00001659321,0.000002575271,0.00001718301,0.00001007348,0.00001559626],"domain_scores_gemma":[0.9999619,0.000009501769,0.00000867139,0.000009301394,0.000003176402,0.000007407646],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008387239,0.00002557705,0.0001440078,0.00008162751,0.000007665442,0.0002627403,0.0001447697,0.0003523907,0.9883302,0.004598488,0.00008339496,0.005885166],"study_design_scores_gemma":[0.00002093925,0.0003128313,0.0008321205,0.000005139121,0.000006444604,0.0006260883,0.0000636363,0.0004838894,0.9877018,0.001314715,0.008621059,0.00001128378],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9455252,0.004318775,0.03048555,0.0004268207,0.0001388699,0.0001308271,0.0002333498,0.0001959291,0.01854471],"genre_scores_gemma":[0.9903757,0.001088828,0.005869037,0.0001191141,0.00001904699,0.00003923219,0.00008512724,0.00001707118,0.002386809],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001268091,"threshold_uncertainty_score":0.004242182,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005822403901360081,"score_gpt":0.213571160208608,"score_spread":0.2077487563072479,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}