{"id":"W1991834928","doi":"10.1021/acsphotonics.5b00143","title":"Evolution of the Ultrafast Photoluminescence of Colloidal Silicon Nanocrystals with Changing Surface Chemistry","year":2015,"lang":"en","type":"article","venue":"ACS Photonics","topic":"Silicon Nanostructures and Photoluminescence","field":"Materials Science","cited_by":69,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Vetenskapsrådet; Canada Foundation for Innovation; Killam Trusts; Alberta Innovates - Technology Futures","keywords":"Photoluminescence; Hydrosilylation; Photochemistry; Alkyl; Materials science; Oxygen; Silicon; Chemistry; Optoelectronics; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004311121,0.0002127059,0.0003492335,0.00002938178,0.00009572491,0.00002525641,0.0006625589,0.0001214048,0.00007353087],"category_scores_gemma":[0.0001716348,0.0001485681,0.00007301266,0.0007010172,0.0004282887,0.000145851,0.0001514773,0.0001223167,0.000003198473],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001176108,"about_ca_system_score_gemma":0.0005071951,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004640676,"about_ca_topic_score_gemma":0.00005041841,"domain_scores_codex":[0.9982461,0.00005615294,0.0003984249,0.0003330686,0.0005858357,0.0003804347],"domain_scores_gemma":[0.9982653,0.00007324335,0.0004719678,0.000678818,0.000400009,0.0001106062],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001217313,0.00004575843,0.008812872,0.0001140571,0.000006546441,0.000001610006,0.0006339345,0.0006061881,0.9895383,0.00004649737,0.00006746537,0.000005051199],"study_design_scores_gemma":[0.0006040292,0.00008148827,0.0009103602,0.0001444462,0.00002710452,0.00005915701,0.0009143898,0.000507811,0.99635,0.0000278329,0.0001918147,0.0001815348],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9984133,0.0002888401,0.00001131101,0.00002571334,0.0003064633,0.0003792334,0.00009421501,0.0000322225,0.0004487014],"genre_scores_gemma":[0.9994167,0.00001010144,0.0002029,0.00002994427,0.00002332824,0.000009575077,0.000003701671,0.00002112936,0.0002826382],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007902512,"threshold_uncertainty_score":0.6058429,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009194450086905922,"score_gpt":0.2093638131483145,"score_spread":0.2001693630614086,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}