{"id":"W1991834928","doi":"10.1021/acsphotonics.5b00143","title":"Evolution of the Ultrafast Photoluminescence of Colloidal Silicon Nanocrystals with Changing Surface Chemistry","year":2015,"lang":"en","type":"article","venue":"ACS Photonics","topic":"Silicon Nanostructures and Photoluminescence","field":"Materials Science","cited_by":69,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Vetenskapsrådet; Canada Foundation for Innovation; Killam Trusts; Alberta Innovates - Technology Futures","keywords":"Photoluminescence; Hydrosilylation; Photochemistry; Alkyl; Materials science; Oxygen; Silicon; Chemistry; Optoelectronics; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002066019,0.0001556626,0.0001046106,0.0001137914,0.00009980376,0.0002854518,0.000144569,0.0002922004,0.0005496693],"category_scores_gemma":[0.0004738552,0.0001389897,0.0001683313,0.00009570552,0.0002917634,0.0002409962,0.0001215852,0.0002853478,0.0001299519],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004012983,"about_ca_system_score_gemma":0.0001817214,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007886025,"about_ca_topic_score_gemma":0.001154813,"domain_scores_codex":[0.9998994,0.0000138494,0.000006842623,0.0000222916,0.00003818992,0.00001957103],"domain_scores_gemma":[0.9997435,0.0001273169,0.00004351785,0.00002183245,0.00004364948,0.00002016018],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002373595,0.000004649532,0.0001686469,0.000009085006,0.000002194803,0.00001263197,0.00001533053,0.00006007238,0.9993334,0.00003930812,0.00000376397,0.0003272434],"study_design_scores_gemma":[0.000003374619,0.00004640994,0.001287093,8.187448e-7,0.000002727835,0.00001890308,0.000010697,0.0007620036,0.9977481,0.00001684777,0.0001014953,0.000001496666],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.998464,0.00009907834,0.0009442629,0.00001544178,0.00000207337,0.000005252181,0.00002679227,0.000009361813,0.000433795],"genre_scores_gemma":[0.9982287,0.00008648972,0.001148947,0.00001415352,0.000001727739,0.000008855844,0.00006419046,0.000007701124,0.0004391257],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007886025,"threshold_uncertainty_score":0.002911687,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009194450086905922,"score_gpt":0.2093638131483145,"score_spread":0.2001693630614086,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}