{"id":"W1992073203","doi":"10.1039/b408687b","title":"Kinetic studies of some substituted hexarhodium carbonyl clusters","year":2004,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Bromide; Iodide; Halide; Stoichiometry; Medicinal chemistry; Solvent; Reaction rate constant; Limiting; Inorganic chemistry; Chloride; Oxygen; Rate-determining step; Catalysis; Organic chemistry; Kinetics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006105642,0.0001703859,0.0002362921,0.00004754025,0.0001694078,0.00001361829,0.0001363933,0.00008686662,0.0002891294],"category_scores_gemma":[0.00001651376,0.0001734112,0.0001072021,0.0001681219,0.000191675,0.0002028491,0.000004028034,0.0002158358,0.000004807026],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001299205,"about_ca_system_score_gemma":0.00008122382,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006046184,"about_ca_topic_score_gemma":0.0000183787,"domain_scores_codex":[0.9990427,0.000008030154,0.0002984882,0.0002402528,0.0001827505,0.0002277586],"domain_scores_gemma":[0.9994572,0.00005897207,0.0001062231,0.0002263685,0.00007775114,0.00007349562],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007779094,0.0002564098,0.0000847574,0.001075197,0.000391862,0.00001214195,0.001783344,0.01109433,0.983042,0.0002808921,0.00002123265,0.001880069],"study_design_scores_gemma":[0.001046727,0.00001442545,0.00002773194,0.0001564395,0.0001417168,0.00001623591,0.001138061,0.0000658842,0.9952335,0.0009213959,0.001041093,0.0001968176],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9756836,0.002661237,0.01400533,0.0006873233,0.0003435976,0.00009560311,0.0001113284,0.0001858792,0.006226076],"genre_scores_gemma":[0.9983817,0.000273736,0.0007122756,0.00003337076,0.0001016513,0.00002500844,0.00002584485,0.0000174621,0.0004289535],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02269807,"threshold_uncertainty_score":0.7071505,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02829715829490883,"score_gpt":0.2827067796238446,"score_spread":0.2544096213289357,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}