{"id":"W1992408303","doi":"10.1021/ma0718604","title":"Styrene/Acrylic Acid Random Copolymers Synthesized by Nitroxide-Mediated Polymerization: Effect of Free Nitroxide on Kinetics and Copolymer Composition","year":2008,"lang":"en","type":"article","venue":"Macromolecules","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":66,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Copolymer; Comonomer; Chemistry; Nitroxide mediated radical polymerization; Styrene; Polymer chemistry; Polymerization; Acrylic acid; Reactivity (psychology); Monomer; Radical polymerization; Reaction rate constant; Kinetics; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002408935,0.0005735584,0.0002578014,0.0001667747,0.0001141609,0.0001623609,0.0001428553,0.0002226152,0.001206596],"category_scores_gemma":[0.0001810978,0.000208896,0.000194142,0.0001643353,0.000115348,0.0002587183,0.0001199559,0.0004484973,0.0003677515],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002026116,"about_ca_system_score_gemma":0.0002432224,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00049822,"about_ca_topic_score_gemma":0.00103771,"domain_scores_codex":[0.9998881,0.00001750748,0.00001165181,0.00002856052,0.00002702939,0.00002707503],"domain_scores_gemma":[0.9998424,0.00002974708,0.00005215327,0.00001172687,0.00002161331,0.00004237282],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004068377,0.000009624982,0.00002658301,0.00001405126,0.000001600476,0.000006233807,0.000004898794,0.00004184248,0.9995442,0.00001396087,0.000003874526,0.0002925178],"study_design_scores_gemma":[0.000004927419,0.00008236044,0.0003345952,0.000001499176,0.000003288661,0.00001088249,0.000001549815,0.0003423574,0.9990262,0.000004596847,0.0001863598,0.000001431043],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9970307,0.0005549221,0.001634093,0.00001865221,0.00001159732,0.00002344365,0.00008135097,0.00005527222,0.000589835],"genre_scores_gemma":[0.9935875,0.0007855804,0.003535274,0.00001808194,0.000007454364,0.00004013866,0.0001770977,0.00003854755,0.001810275],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001206596,"threshold_uncertainty_score":0.004036486,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004564495622572643,"score_gpt":0.2026329423049742,"score_spread":0.1980684466824016,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}