{"id":"W1992410696","doi":"10.1039/c1ja10252d","title":"UV photochemical generation of volatile cadmium species","year":2011,"lang":"en","type":"article","venue":"Journal of Analytical Atomic Spectrometry","topic":"Analytical chemistry methods development","field":"Chemistry","cited_by":52,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"","keywords":"Detection limit; Chemistry; Argon; Analyte; Analytical Chemistry (journal); Acetic acid; Hydrogen; Cadmium; Chromatography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001412321,0.0002650703,0.0001926914,0.0002162032,0.0002935435,0.0002355588,0.000287566,0.0002556452,0.001493974],"category_scores_gemma":[0.000248684,0.0001958003,0.0001962831,0.0001982265,0.000270523,0.0001469312,0.0003397244,0.0006019977,0.0002308806],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003664929,"about_ca_system_score_gemma":0.0001692157,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003963558,"about_ca_topic_score_gemma":0.0007026735,"domain_scores_codex":[0.9998537,0.00001642694,0.000004694635,0.00004910328,0.00004289233,0.00003320556],"domain_scores_gemma":[0.9998572,0.0000577036,0.00002142092,0.00002513605,0.00002441384,0.00001403008],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000174708,0.000003933421,0.0001066518,0.00002468785,0.000001971752,0.00002031344,0.00001405212,0.00003942684,0.9987154,0.00008184826,0.00002875208,0.0009454613],"study_design_scores_gemma":[0.00000161294,0.00002728014,0.0003714667,0.000001222743,0.000001740535,0.00002462065,0.000006164326,0.0001603444,0.9989154,0.00001685427,0.0004721184,0.000001046126],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9762495,0.0008308056,0.01710463,0.00008851563,0.0000397537,0.00005886815,0.0003139522,0.0002259153,0.005088149],"genre_scores_gemma":[0.9892342,0.0004980369,0.005977568,0.00003419993,0.000009454396,0.0000411805,0.0002292124,0.0000335213,0.003942609],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001493974,"threshold_uncertainty_score":0.00499779,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06497187206232659,"score_gpt":0.2880361078981201,"score_spread":0.2230642358357935,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}