{"id":"W1992450122","doi":"10.1021/jo034119c","title":"On the Regiochemistry of Nucleophilic Attack on 2-Halo π-Allyl Complexes. 4. The Effect of Silver Acetate and Nucleophile Concentrations in Competitive Nucleophilic Attack with Malonate and Phenoxide Nucleophiles","year":2003,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Nucleophile; Chemistry; Methoxide; Malonate; Dimethyl malonate; Medicinal chemistry; Triphenylphosphine; Propene; Regioselectivity; Photochemistry; Organic chemistry; Catalysis; Palladium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000880316,0.000374651,0.0006267666,0.00005384168,0.0002129685,0.00003836042,0.0005975444,0.0001460809,0.000901881],"category_scores_gemma":[0.0004612132,0.0002002374,0.0001511153,0.0005458171,0.0008981415,0.00008274282,0.00008841769,0.0007418123,0.00000423882],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001045376,"about_ca_system_score_gemma":0.0001037775,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007288936,"about_ca_topic_score_gemma":0.000006871236,"domain_scores_codex":[0.997875,0.0001733378,0.00075353,0.0002730356,0.0006285562,0.0002965865],"domain_scores_gemma":[0.9962394,0.001783579,0.001010901,0.0006444327,0.0001910677,0.0001306146],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008535429,0.0002602707,0.003373606,0.0004335246,0.000623464,0.00002978036,0.001794845,0.0004015988,0.9906709,0.0007719659,0.000549652,0.0002369186],"study_design_scores_gemma":[0.002838475,0.00022556,0.001665629,0.0004324601,0.0003478891,0.0004195427,0.002555475,0.000127822,0.9905452,0.0001512371,0.0004234679,0.0002672922],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9899149,0.0006933961,0.000003684127,0.001234685,0.00001781501,0.0001613931,0.00004004519,0.00001156309,0.007922545],"genre_scores_gemma":[0.9991582,0.0003946205,0.00001291041,0.000143915,0.00005644197,0.000003938554,0.000006971263,0.00004633463,0.0001766447],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00924335,"threshold_uncertainty_score":0.9874964,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01083746944756035,"score_gpt":0.2261365724457695,"score_spread":0.2152991029982092,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}