{"id":"W1992584731","doi":"10.1021/jo0265129","title":"First Experimental and Theoretical Evidence of a Deactivating Enone Dienophile in the Transannular Diels−Alder Reaction","year":2003,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Info-communications Media Development Authority","keywords":"Chemistry; Enone; Diels–Alder reaction; Photochemistry; Computational chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001005388,0.0001206261,0.0002257849,0.00002024483,0.00008621307,0.00001580171,0.0002915471,0.00008049511,0.0007364989],"category_scores_gemma":[0.0007604589,0.00006997286,0.00008346495,0.0002254373,0.0001749796,0.00009902411,0.00002255985,0.0003344158,5.618131e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006557853,"about_ca_system_score_gemma":0.00004215364,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006029933,"about_ca_topic_score_gemma":5.465516e-7,"domain_scores_codex":[0.9989555,0.00005632999,0.0004114648,0.0001001892,0.0003363041,0.000140174],"domain_scores_gemma":[0.9983913,0.0009451389,0.0003210542,0.0002509032,0.00004920445,0.00004239186],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007368952,0.000139234,0.0003522388,0.00007047694,0.00004535235,0.000007639357,0.002312938,0.000002005596,0.9964463,0.00005254768,0.00001092222,0.0004866694],"study_design_scores_gemma":[0.0003018882,0.00002853237,0.000199741,0.0002202158,0.0001019544,0.0004745225,0.009556491,0.00001760096,0.9887922,0.00016547,0.00006329097,0.00007809557],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9927998,0.004072823,0.0001382436,0.000318258,0.00001252135,0.00002517656,8.78182e-7,0.000003034426,0.002629283],"genre_scores_gemma":[0.9994876,0.0003225672,0.0000621488,0.00001909457,0.00007263172,0.000001633944,2.728631e-7,0.00001268618,0.00002133392],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007654089,"threshold_uncertainty_score":0.8064146,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0119592572406672,"score_gpt":0.2335596225665003,"score_spread":0.2216003653258331,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}