{"id":"W1992722368","doi":"10.1021/ic0111684","title":"Reduction of [VO<sub>2</sub>(ma)<sub>2</sub>]<sup>-</sup> and [VO<sub>2</sub>(ema)<sub>2</sub>]<sup>-</sup> by Ascorbic Acid and Glutathione:  Kinetic Studies of Pro-Drugs for the Enhancement of Insulin Action","year":2002,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Vanadium and Halogenation Chemistry","field":"Chemistry","cited_by":64,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Ascorbic acid; Maltol; Reaction rate constant; Glutathione; Inorganic chemistry; Vanadium; Kinetics; Electron paramagnetic resonance; Nuclear chemistry; Medicinal chemistry; Stereochemistry; Organic chemistry; Nuclear magnetic resonance; Enzyme","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001903091,0.0003040264,0.0002969625,0.0001104698,0.00007845413,0.0004036262,0.0004173949,0.0004084911,0.0009298553],"category_scores_gemma":[0.0003759339,0.0001821798,0.00023945,0.0001737693,0.0001707851,0.0003048812,0.0001875211,0.0004258722,0.000248652],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002435306,"about_ca_system_score_gemma":0.0001583571,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007550803,"about_ca_topic_score_gemma":0.001008498,"domain_scores_codex":[0.999849,0.0000265451,0.00001459465,0.00003502129,0.00003856885,0.00003633212],"domain_scores_gemma":[0.9998959,0.00002151085,0.00002559192,0.00001186593,0.00003169773,0.00001340281],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001332235,0.00001277308,0.0001960011,0.00006770148,0.00001238575,0.00003030975,0.00002746562,0.000147747,0.9980577,0.0001285644,0.00002177407,0.001164335],"study_design_scores_gemma":[0.000004068748,0.00009509179,0.0007015017,0.000002949473,0.000007049023,0.00004345609,0.00002249335,0.0009197037,0.9973513,0.00003585656,0.0008129851,0.000003632653],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910758,0.002076145,0.005175738,0.00008501487,0.00003683155,0.00003562558,0.0001520589,0.00006606345,0.001296738],"genre_scores_gemma":[0.9935069,0.000658027,0.003289154,0.00003643923,0.000007477211,0.00002003098,0.0001577813,0.00002457362,0.002299662],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009298553,"threshold_uncertainty_score":0.003110707,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01925854982886682,"score_gpt":0.241695461092995,"score_spread":0.2224369112641282,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}