{"id":"W1992934175","doi":"10.1016/s0006-291x(02)00874-4","title":"Diaphorase catalyzed biotransformation of RDX via N-denitration mechanism","year":2002,"lang":"en","type":"article","venue":"Biochemical and Biophysical Research Communications","topic":"Chemical Reactions and Isotopes","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":54,"is_retracted":false,"has_abstract":false,"ca_institutions":"Biotechnology Research Institute","funders":"","keywords":"Chemistry; Biotransformation; Flavin mononucleotide; Nitrite; Hydroxylation; Formaldehyde; Photochemistry; Flavin group; Medicinal chemistry; Stereochemistry; Organic chemistry; Enzyme","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002609168,0.0003373454,0.0002286968,0.0001026826,0.0001467598,0.000143342,0.0002210804,0.0002422566,0.0006593619],"category_scores_gemma":[0.0001681638,0.0001047235,0.0001924096,0.00009077764,0.0001767485,0.0002299399,0.0002330267,0.0003353405,0.0002424066],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005277777,"about_ca_system_score_gemma":0.0005452493,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002322917,"about_ca_topic_score_gemma":0.003290164,"domain_scores_codex":[0.9998773,0.00002102045,0.00000865719,0.00003211044,0.00002792689,0.00003290491],"domain_scores_gemma":[0.9999366,0.00001365156,0.00001376301,0.00001699223,0.00001136384,0.000007686622],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009987628,0.00002202284,0.0003014617,0.00003428072,0.000006404764,0.00008787654,0.00002266768,0.0002752182,0.9950011,0.0005811219,0.00005636438,0.003511482],"study_design_scores_gemma":[0.000002808512,0.00003847575,0.0003257775,9.464405e-7,0.000002612045,0.00005353691,0.000003420751,0.0002893074,0.9986526,0.00003535062,0.0005932488,0.000001918985],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9826244,0.0008511742,0.01142643,0.0001207601,0.00003747408,0.00004803798,0.0001680052,0.0001112953,0.004612475],"genre_scores_gemma":[0.9911748,0.0004655532,0.00396697,0.00003243235,0.000003200018,0.00001782958,0.0001829547,0.000009243659,0.004146927],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002322917,"threshold_uncertainty_score":0.004618764,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.2830971193768711,"score_gpt":0.481692941096335,"score_spread":0.1985958217194639,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}