{"id":"W1992976553","doi":"10.1021/jp026267x","title":"Kinetics and Mechanism of the Addition of Aliphatic Amines to Transient Silenes","year":2003,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Molecular Junctions and Nanostructures","field":"Engineering","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Reaction rate constant; Photochemistry; Tetrahydrofuran; Flash photolysis; Arrhenius equation; Solvent; Hexane; Reaction mechanism; Chemical kinetics; Kinetics; Organic chemistry; Activation energy; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002988381,0.0004657273,0.000279163,0.0002041066,0.0001371679,0.0003412004,0.0003608363,0.0003489442,0.002496961],"category_scores_gemma":[0.0004148099,0.0002736812,0.0003240553,0.00009228789,0.0002367461,0.0004232456,0.0002000766,0.000537759,0.0008804157],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005106652,"about_ca_system_score_gemma":0.0001996617,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008736907,"about_ca_topic_score_gemma":0.0007952592,"domain_scores_codex":[0.9998118,0.00002317759,0.00001029504,0.00005241015,0.00004956417,0.00005279199],"domain_scores_gemma":[0.9996631,0.0001524249,0.00007635135,0.00002325553,0.00004576075,0.00003906978],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001037823,0.00001677947,0.0002304344,0.00005470379,0.000007314568,0.00003882107,0.00004228459,0.000392875,0.9973915,0.0001424281,0.0000364908,0.001542502],"study_design_scores_gemma":[0.000004607906,0.0001142732,0.001124663,0.00000309188,0.000005474462,0.00003371128,0.00001207622,0.002266886,0.9959741,0.00002308757,0.0004331224,0.000004943713],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.990832,0.001073634,0.005173656,0.00006886369,0.00002316512,0.00007144389,0.0002522923,0.0001751116,0.002329902],"genre_scores_gemma":[0.9937552,0.0007493178,0.001622356,0.00002346594,0.000007917493,0.00005445027,0.0002088061,0.00002598632,0.003552527],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002496961,"threshold_uncertainty_score":0.008353174,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003741486069530271,"score_gpt":0.1821403644483381,"score_spread":0.1783988783788079,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}