{"id":"W1993002166","doi":"10.1002/pen.21941","title":"CO<sub>2</sub>‐derived latent nitrogen nucleophiles for controlled cross‐linking of brominated poly(isobutylene‐<i>co</i>‐isoprene)","year":2011,"lang":"en","type":"article","venue":"Polymer Engineering and Science","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Isobutylene; Nucleophile; Thermal decomposition; Isoprene; Thermogravimetric analysis; Chemistry; Carbamate; Polymer chemistry; Organic chemistry; Polymer; Materials science; Copolymer; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0003994274,0.0002691907,0.0004920993,0.000357328,0.0001228694,0.00006356982,0.0003781049,0.0001096162,0.00001833515],"category_scores_gemma":[0.0002668929,0.0002680387,0.0001738512,0.0005330521,0.0002991368,0.0002383673,0.0000677439,0.0001273202,0.000004006033],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005546122,"about_ca_system_score_gemma":0.0000551874,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003356308,"about_ca_topic_score_gemma":9.958363e-7,"domain_scores_codex":[0.9981433,0.000009421623,0.0005189066,0.0004596349,0.0003546544,0.0005141427],"domain_scores_gemma":[0.9989527,0.0001766733,0.0001496217,0.0003427312,0.0001605393,0.0002177474],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007989025,0.00002910663,0.00126425,0.00008541388,0.00006838696,0.000001484474,0.0005366786,0.001887743,0.9948097,0.0006850538,0.000002104197,0.0005501466],"study_design_scores_gemma":[0.00140858,0.00002976162,0.001146983,0.00006281379,0.0000557192,0.000007342983,0.00002223674,0.1308651,0.8661038,0.00003624762,0.000005857937,0.0002554942],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9825752,0.001386992,0.01516641,0.00001055978,0.0001749318,0.0002479854,0.00005070026,0.0002060301,0.0001811565],"genre_scores_gemma":[0.998671,0.00004301949,0.001065254,0.00001994997,0.00005011454,0.00006242435,0.00001505506,0.0000456243,0.00002755693],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1289774,"threshold_uncertainty_score":0.9999772,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01530073865358306,"score_gpt":0.2330823133858839,"score_spread":0.2177815747323008,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}